EC Number   |
Activating Compound |
Reference |
|---|
    1.14.15.1 | bis(2-ethylhexyl) sulfosuccinate |
improves the initial activity of P450cam in two-phase emulsions with initial camphor concentrations of 5-15 mM. P450cam is activated in the surfactant-free emulsions, and addition of bis(2-ethylhexyl) sulfosuccinate sodium salt improves the activity even further, at least over the range of camphor concentrations for which initial rates are readily measurable in all media. The largest rate enhancement is 4.5fold. Nearly 50times more product is formed in the surfactant-stabilized emulsions than is achieved in aqueous buffer |
702799 |
| 1.14.15.1 | cumene hydroperoxide |
considerable amount of the putative Cpd II species accumulates, even at pH 7.4. By contrast, reactions with meta-chloroperbenzoic acid at pH 7.4 yield very little of the ca. 420 nm species, unless methanol is included |
704713 |
| 1.14.15.1 | glycerol |
activates in vivo and in vitro |
671535 |
| 1.14.15.1 | methanol |
reaction with meta-chloroperbenzoic acid in the presence of methanol (3% or ca. 1 M after mixing) at pH 7.4 and 25°C results in the accumulation of a considerable fraction of the P450cam as the putative Cpd II species |
704713 |
| 1.14.15.1 | more |
involvement of X-proline isomerization in enzyme function |
706783 |
| 1.14.15.1 | tetrahydrofuran |
activation |
347690 |
