4.1.1.11	additional information	requires pyruvate as a covalently bound, catalytically active prosthetic group, pyruvoyl-dependent enzyme, the pyruvoyl group is generated at a specific internal serine residue of the inactive pi-protein with the coincident cleavage of the Gly-Ser bond	649350	
4.1.1.11	additional information	the ancillary protein PanM (formerly YhhK) is required in vitro and in vivo for cleavage of the L-aspartate-alpha-decarboxylase zymogen	747435	
4.1.1.11	additional information	the enzyme requires PanZ, an activator involved in the cleavage of ADCE	746859	
4.1.1.11	additional information	the translated inactive proenzyme, pi-enzyme, self-processes to create its own covalently bound prosthetic group, a pyruvoyl cofactor, mechanism	650998	
4.1.1.11	pyridoxal 5'-phosphate	-	727784, 749304	
4.1.1.11	pyridoxal 5'-phosphate	dependent on	748086	
4.1.1.11	pyridoxal 5'-phosphate	tautomers of the internal aldimine between PLP and enzyme, overview	727622	
4.1.1.11	pyridoxal 5'-phosphate	the enzyme contains pyridoxal 5'-phosphate	744560	
4.1.1.11	pyruvoyl cofactor	-	747128	
4.1.1.11	pyruvoyl cofactor	dependent on	728571, 747497	
4.1.1.11	pyruvoyl cofactor	dependent on, the enzyme contains a covalently-bound pyruvoyl cofactor	728266	
4.1.1.11	pyruvoyl cofactor	dependent on. Pathway for the formation of the pyruvoyl-dependent cofactor in ADC: the beta-hydroxyl of Ser25 attacks the carbonyl of the previous amino-acid residue (i) to form an oxyoxazolidine intermediate, which decomposes (ii) to form an ester intermediate. E1cB elimination (iii) forms a N-terminal dehydroalanyl residue which is hydrolysed (iv) to form the pyruvoyl cofactor (the alpha'-chain). The ester intermediate can also be hydrolysed to yield the inactive alpha'-chain	726592	
4.1.1.11	pyruvoyl cofactor	the enzyme PanD is synthesized as pro-PanD, which undergoes an auto-proteolytic cleavage at residue Ser25 to yield the catalytic pyruvoyl moiety of the enzyme	728327	
4.1.1.11	pyruvoyl cofactor	the pyruvoyl group is required for catalysis	726617