4.2.1.B8	(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoic acid	poor substrate	Convallaria majalis	?	-	?	407613	
4.2.1.B8	(9Z,11E,13R)-13-hydroperoxy-9,11-octadecadienoate	is utilized more slowly than (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate	Allium sativum	(9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O	i.e. etheroleic acid	?	407617	
4.2.1.B8	(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate	-	Allium sativum	(9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O	i.e. etheroleic acid	?	406971	
4.2.1.B8	(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate	(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate is the preferred substrate	Convallaria majalis	(9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O	i.e. etheroleic acid	?	406971	
4.2.1.B8	(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate	an essentially complete loss of isotope is noted with the (14R)-deuterated precursor, whereas incubation of the (14S)-deuterated precursor affords products that retain most of the deuterium label	Allium sativum	(9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O	i.e. etheroleic acid	?	406971	
4.2.1.B8	(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate	an essentially complete loss of isotope is noted with the (14R)-deuterated precursor, whereas incubation of the (14S)-deuterated precursor affords products that retained most of the deuterium label	Allium sativum	(9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O	i.e. etheroleic acid	?	406971	
4.2.1.B8	(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate	no activity with (9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate	Allium sativum	(9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O	i.e. etheroleic acid	?	406971	
4.2.1.B8	(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate	the enzyme uses preferentially 13-hydroperoxides as substrates and efficiently converts them into divinyl ether fatty acids	Allium sativum	(9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O	i.e. etheroleic acid	?	406971	
4.2.1.B8	(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate	the S enantiomer is a much better substrate for the divinyl ether synthase compared to the R enantiomer. Incubation of (9Z,11E,13S)-[18O2]hydroperoxy-9,11-octadecadienoic acid leads to the formation of etheroleic acid which retains 18O in the ether oxygen. An intermediary role of an epoxyallylic cation in etheroleic acid biosynthesis is postulated	Allium sativum	(9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + (9E,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O	two isomers of etheroleic acid are isolated	?	407619	
4.2.1.B8	(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid	-	Ranunculus acris	(9Z,11E)-12-[(1'Z)-hexenyloxy]-9,11-dodecadienoic acid	i.e. (omega5Z)-etherolenic acid	?	429105