5.1.3.2 epimerization - 673409, 702074, 702141, 704314, 713793 5.1.3.2 epimerization of uridine diphosphate (UDP)-glucose to a galactose derivated UDP-galactose 673283 5.1.3.2 epimerization specificity for carbon 4, forming a 4-hexosulose intermediate - 5.1.3.2 epimerization The reaction mechanism of UGE is thought to occur via transfer of the 4'-OH hydrogen of the sugar to the nicotinamide ring of noncovalently bound NAD+, rotation of the resulting 4'-ketopyranose intermediate in the active site, and transfer of the hydride from the nicotinamide ring of NADH back to C-4 of the sugar. 674580 5.1.3.2 additional information catalyses the interconversion of UDP-Gal and UDPGlc -, 661017, 671798 5.1.3.2 additional information HvUGE also catalyses the interconversion of UDP-GalNAc and UDP-GlcNAc, although it is not known if this has any biological significance. -, 661017