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Literature summary extracted from

  • Ferguson, K.L.; Arunrattanamook, N.; Marsh, E.N.
    Mechanism of the novel prenylated flavin-containing enzyme ferulic acid decarboxylase probed by isotope effects and linear free-energy relationships (2016), Biochemistry, 55, 2857-2863 .
    View publication on PubMed

Organism

EC Number Organism UniProt Comment Textmining
4.1.1.102 Saccharomyces cerevisiae Q03034
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.1.1.102 3-methoxycinnamic acid
-
 Saccharomyces cerevisiae 3-methoxystyrene + CO2
-
 ?
4.1.1.102 3-nitrocinnamic acid
-
 Saccharomyces cerevisiae 3-nitrostyrene + CO2
-
 ?
4.1.1.102 4-aminocinnamic acid
-
 Saccharomyces cerevisiae 4-aminostyrene + CO2
-
 ?
4.1.1.102 4-bromocinnamic acid
-
 Saccharomyces cerevisiae 4-bromostyrene + CO2
-
 ?
4.1.1.102 4-chlorocinnamic acid
-
 Saccharomyces cerevisiae 4-chlorostyrene + CO2
-
 ?
4.1.1.102 4-coumarate
-
 Saccharomyces cerevisiae 4-vinylphenol + CO2
-
 ?
4.1.1.102 4-cyanocinnamic acid
-
 Saccharomyces cerevisiae 4-cyanostyrene + CO2
-
 ?
4.1.1.102 4-fluorocinnamic acid
-
 Saccharomyces cerevisiae 4-fluorostyrene + CO2
-
 ?
4.1.1.102 4-formylcinnamic acid
-
 Saccharomyces cerevisiae 4-formylstyrene + CO2
-
 ?
4.1.1.102 4-hydroxycinnamic acid
-
 Saccharomyces cerevisiae 4-hydroxystyrene + CO2
-
 ?
4.1.1.102 4-methoxycinnamic acid
-
 Saccharomyces cerevisiae 4-methoxystyrene + CO2
-
 ?
4.1.1.102 4-methylcinnamic acid
-
 Saccharomyces cerevisiae 4-methylstyrene + CO2
-
 ?
4.1.1.102 4-nitrocinnamic acid
-
 Saccharomyces cerevisiae 4-nitrostyrene + CO2
-
 ?
4.1.1.102 ferulate
-
 Saccharomyces cerevisiae 4-vinylguaiacol + CO2
-
 ?
4.1.1.102 additional information CO2 release must occur after protonation of the product. For a range of para- and meta-substituted phenylacrylic acids, the log(kcat/KM) value for the reaction correlates well with the Hammett delta- parameter with rho = 0.39 and r2 = 0.93 consistent with the rate-determining step being the formation of styrene from the prenylated flavin-product adduct through a cycloelimination reaction Saccharomyces cerevisiae ?
-
 ?
4.1.1.102 trans-cinnamate
-
 Saccharomyces cerevisiae styrene + CO2
-
 ?

Synonyms

EC Number Synonyms Comment Organism
4.1.1.102 FDC1
-
 Saccharomyces cerevisiae

kcat/KM [mM/s]

EC Number kcat/KM Value [1/mMs-1] kcat/KM Value Maximum [1/mMs-1] Substrate Comment Organism Structure
4.1.1.102 4.55
-
 4-hydroxycinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 8.7
-
 3-nitrocinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 8.7
-
 4-formylcinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 12.4
-
 4-aminocinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 12.8
-
 4-cyanocinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 14.3
-
 3-nitrocinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 19.7
-
 4-chlorocinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 21.4
-
 4-bromocinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 24.5
-
 trans-cinnamate 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 27
-
 3-methoxycinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 27
-
 4-methylcinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 27.5
-
 4-fluorocinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae
4.1.1.102 28.1
-
 4-methoxycinnamic acid 25°C, pH 7.0 Saccharomyces cerevisiae