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Literature summary extracted from

  • Hedegard, E.; Ryde, U.
    Targeting the reactive intermediate in polysaccharide monooxygenases (2017), J. Biol. Inorg. Chem., 22, 1029-1037.
    View publication on PubMed

Metals/Ions

EC Number Metals/Ions Comment Organism Structure
1.14.99.54 Cu2+ the calculated dissociation energies suggest that the reactive intermediate is either a Cu(II)-oxyl, a Cu(III)-oxyl, or a Cu(III)-hydroxide, indicating that O-O bond breaking occurs before the C-H activation step Panus similis
1.14.99.56 Cu2+ the calculated dissociation energies suggest that the reactive intermediate is either a Cu(II)-oxyl, a Cu(III)-oxyl, or a Cu(III)-hydroxide, indicating that O-O bond breaking occurs before the C-H activation step Panus similis

Organism

EC Number Organism UniProt Comment Textmining
1.14.99.54 Panus similis A0A0S2GKZ1
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1.14.99.56 Panus similis A0A0S2GKZ1
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-