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Literature summary extracted from

  • Ikeyama, S.; Amao, Y.
    An artificial co-enzyme based on the viologen skeleton for highly efficient CO2 reduction to formic acid with formate dehydrogenase (2017), ChemCatChem, 9, 833-838.
No PubMed abstract available

KM Value [mM]

EC Number KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
1.17.1.9 0.017
-
 reduced 1,1'-diaminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 0.118
-
 reduced 1-methyl-1'-aminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 0.212
-
 reduced methyl viologen at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 0.292
-
 reduced 1-methyl-1'-carboxymethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 0.371
-
 reduced 1,1'-dicarboxyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
1.17.1.9 CO2 + NADH [Candida] boidinii
-
 formate + NAD+
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
1.17.1.9 [Candida] boidinii O13437
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.17.1.9 CO2 + NADH
-
 [Candida] boidinii formate + NAD+
-
 ?
1.17.1.9 CO2 + reduced 1,1'-diaminoethyl-4,4'-bipyridinium salt
-
 [Candida] boidinii formate + 1,1'-diaminoethyl-4,4'-bipyridinium salt
-
 ?
1.17.1.9 CO2 + reduced 1,1'-dicarboxyl-4,4'-bipyridinium salt
-
 [Candida] boidinii formate + 1,1'-dicarboxyl-4,4'-bipyridinium salt
-
 ?
1.17.1.9 CO2 + reduced 1,1'-diphenyl-4,4'-bipyridinium salt
-
 [Candida] boidinii formate + 1,1'-diphenyl-4,4'-bipyridinium salt
-
 ?
1.17.1.9 CO2 + reduced 1-methyl-1'-aminoethyl-4,4'-bipyridinium salt
-
 [Candida] boidinii formate + 1-methyl-1'-aminoethyl-4,4'-bipyridinium salt
-
 ?
1.17.1.9 CO2 + reduced 1-methyl-1'-carboxymethyl-4,4'-bipyridinium salt
-
 [Candida] boidinii formate + 1-methyl-1'-carboxymethyl-4,4'-bipyridinium salt
-
 ?
1.17.1.9 CO2 + reduced methyl viologen
-
 [Candida] boidinii formate + methyl viologen
-
 ?

Synonyms

EC Number Synonyms Comment Organism
1.17.1.9 FDH
-
 [Candida] boidinii

Turnover Number [1/s]

EC Number Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
1.17.1.9 0.005
-
 reduced 1,1'-dicarboxyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 0.025
-
 reduced 1-methyl-1'-carboxymethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 0.032
-
 reduced methyl viologen at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 0.038
-
 reduced 1-methyl-1'-aminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 0.072
-
 reduced 1,1'-diaminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii

Cofactor

EC Number Cofactor Comment Organism Structure
1.17.1.9 NAD+
-
 [Candida] boidinii

kcat/KM [mM/s]

EC Number kcat/KM Value [1/mMs-1] kcat/KM Value Maximum [1/mMs-1] Substrate Comment Organism Structure
1.17.1.9 0.09
-
 reduced 1-methyl-1'-carboxymethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 0.15
-
 reduced methyl viologen at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 0.32
-
 reduced 1-methyl-1'-aminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 1.55
-
 reduced 1,1'-dicarboxyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.17.1.9 4.17
-
 reduced 1,1'-diaminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii