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Literature summary extracted from
- Probing the mechanism of cyanobacterial aldehyde decarbonylase using a cyclopropyl aldehyde (2013), J. Am. Chem. Soc., 135, 5234-5237.
Inhibitors
| EC Number | Inhibitors | Comment | Organism | Structure |
|---|---|---|---|---|
| 4.1.99.5 | 2-(2-tetradecylcyclopropyl)acetaldehyde | a cyclopropyl analogue of octadecanal in which the cyclopropyl group is positioned beta to the carbonyl group. The compound is partitioned between turnover and irreversible inhibition of the enzyme, mechanism of inactivation, overview. Formation of 1-octadecene at low level appears to be described by first-order kinetics might be involved in enzyme inhibition | Nostoc punctiforme |  |
Organism
| EC Number | Organism | UniProt | Comment | Textmining |
|---|---|---|---|---|
| 4.1.99.5 | Nostoc punctiforme | - |
- |
- |
Substrates and Products (Substrate)
| EC Number | Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|---|
| 4.1.99.5 | 2-(2-tetradecylcyclopropyl)acetaldehyde + 2 NADH + O2 + 2 H+ | formation of 1-octadecene at low level appears to be described by first-order kinetics, 1-octadecene might be involved in enzyme inhibition | Nostoc punctiforme | 1-methyl-2-tetradecylcyclopropane + formate + H2O + 2 NAD+ | GC-MS poduct analysis | ? | |
| 4.1.99.5 | octadecanal + O2 + 2 NADH + 2 H+ | with reducing system NADH/phenazine methosulfate | Nostoc punctiforme | heptadecane + formate + H2O + 2 NAD+ | GC-MS poduct analysis | ? | |
| 4.1.99.5 | pentadecanal + O2 + 2 NADH + 2 H+ | with reducing system NADH/phenazine methosulfate | Nostoc punctiforme | tetradecane + formate + H2O + 2 NAD+ | GC-MS poduct analysis | ? | |
Synonyms
| EC Number | Synonyms | Comment | Organism |
|---|---|---|---|
| 4.1.99.5 | CAD | - |
Nostoc punctiforme |
| 4.1.99.5 | cyanobacterial aldehyde decarbonylase | - |
Nostoc punctiforme |
Temperature Optimum [°C]
| EC Number | Temperature Optimum [°C] | Temperature Optimum Maximum [°C] | Comment | Organism |
|---|---|---|---|---|
| 4.1.99.5 | 37 | - |
assay at | Nostoc punctiforme |
pH Optimum
| EC Number | pH Optimum Minimum | pH Optimum Maximum | Comment | Organism |
|---|---|---|---|---|
| 4.1.99.5 | 7.2 | - |
assay at | Nostoc punctiforme |
Cofactor
| EC Number | Cofactor | Comment | Organism | Structure |
|---|---|---|---|---|
| 4.1.99.5 | NADH | - |
Nostoc punctiforme | |
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Release 2023.1 (January 2023)
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