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Literature summary extracted from

  • Miao, Y.; Geertsema, E.M.; Tepper, P.G.; Zandvoort, E.; Poelarends, G.J.
    Promiscuous catalysis of asymmetric Michael-type additions of linear aldehydes to beta-nitrostyrene by the proline-based enzyme 4-oxalocrotonate tautomerase (2013), ChemBioChem, 14, 191-194.
    View publication on PubMed

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
5.3.2.6 (2Z,4E)-2-hydroxyhexa-2,4-dienedioate Bacillus subtilis
-
 (3E)-2-oxohex-3-enedioate
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
5.3.2.6 Bacillus subtilis
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
5.3.2.6 (2Z,4E)-2-hydroxyhexa-2,4-dienedioate
-
 Bacillus subtilis (3E)-2-oxohex-3-enedioate
-
 ?
5.3.2.6 acetaldehyde + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (3S)-4-nitro-3-phenylbutanal
-
 ?
5.3.2.6 butanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R,3S)-2-ethyl-4-nitro-3-phenylbutanal
-
 ?
5.3.2.6 heptanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R)-2-[(1S)-2-nitro-1-phenylethyl]heptanal
-
 ?
5.3.2.6 hexanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R)-2-[(1S)-2-nitro-1-phenylethyl]hexanal
-
 ?
5.3.2.6 octanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R)-2-[(1S)-2-nitro-1-phenylethyl]octanal
-
 ?
5.3.2.6 pentanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R)-2-[(1S)-2-nitro-1-phenylethyl]pentanal
-
 ?
5.3.2.6 propanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R,3S)-2-methyl-4-nitro-3-phenylbutanal
-
 ?

Synonyms

EC Number Synonyms Comment Organism
5.3.2.6 4-OT
-
 Bacillus subtilis
5.3.2.6 4-oxalocrotonate tautomerase
-
 Bacillus subtilis