BRENDA - Enzyme Database show

Epoxidation of fatty acids, fatty methyl esters, and alkenes by immobilized oat seed peroxygenase

Piazza, G.J.; Nunez, A.; Foglia, T.A.; J. Mol. Catal. B 21, 143-151 (2003)
No PubMed abstract available

Data extracted from this reference:

Localization
EC Number
Localization
Commentary
Organism
GeneOntology No.
Textmining
1.11.2.3
membrane
-
Avena sativa
16020
-
Organism
EC Number
Organism
Primary Accession No. (UniProt)
Commentary
Textmining
1.11.2.3
Avena sativa
-
-
-
Source Tissue
EC Number
Source Tissue
Commentary
Organism
Textmining
1.11.2.3
seed
-
Avena sativa
-
Substrates and Products (Substrate)
EC Number
Substrates
Commentary Substrates
Literature (Substrates)
Organism
Products
Commentary (Products)
Literature (Products)
Organism (Products)
Reversibility
1.11.2.3
2-methylhept-1-ene + tert-butyl hydroperoxide
-
712776
Avena sativa
2-methyl-2-pentyloxirane + ?
-
-
-
?
1.11.2.3
cis-2-heptene + tert-butyl hydroperoxide
-
712776
Avena sativa
2-butyl-3-methyl-cis-oxirane + ?
93.9% yield
-
-
?
1.11.2.3
cis-3-heptene + tert-butyl hydroperoxide
-
712776
Avena sativa
2-ethyl-3-propyl-cis-oxirane + ?
72.7% yield
-
-
?
1.11.2.3
cyclohexene + tert-butyl hydroperoxide
-
712776
Avena sativa
7-oxabicyclo-[4.1.0]-heptane + ?
70.5% yield
-
-
?
1.11.2.3
hept-1-ene + tert-butyl hydroperoxide
-
712776
Avena sativa
2-pentyloxirane + ?
2.8% yield
-
-
?
1.11.2.3
linoleate + tert-butyl hydroperoxide
-
712776
Avena sativa
(9Z)-12,13-epoxyoctadec-9-enoate + (12Z)-9,10-epoxyoctadec-12-enoate + 9,10-12,13-diepoxy-octadecanoate + ?
23.4% yield, 25.4% yield and 46.7% yield, respectively
-
-
?
1.11.2.3
linoleate methyl ester + tert-butyl hydroperoxide
-
712776
Avena sativa
methyl 12,13-epoxy-9(Z)-octadecenoate + methyl 9,10-epoxy-12(Z)-octadecenoate + methyl 9,10-12,13-diepoxyoctadecanoate + ?
17.6% yield, 21.9% yield and 49.5% yield, respectively
-
-
?
1.11.2.3
linolenate + tert-butyl hydroperoxide
-
712776
Avena sativa
additional information
0.6% monoepoxy product and 91.6% diepoxy product
-
-
?
1.11.2.3
methyl (13Z)-docos-13-enoate + tert-butyl hydroperoxide
-
712776
Avena sativa
methyl behenate 13,14-epoxide + H2O
26.9% yield
-
-
?
1.11.2.3
methyl linolenate + tert-butyl hydroperoxide
-
712776
Avena sativa
additional information
14.3% monoepoxy product and 78.3% diepoxy product
-
-
?
1.11.2.3
oleate + tert-butyl hydroperoxide
-
712776
Avena sativa
methyl 9,10-epoxyoctadecanoate + ?
99.8% yield
-
-
?
1.11.2.3
oleate methyl ester + tert-butyl hydroperoxide
-
712776
Avena sativa
methyl 9,10-epoxyoctadecanoate + ?
93.9% yield
-
-
?
1.11.2.3
ricinoleate + tert-butyl hydroperoxide
-
712776
Avena sativa
9,10-epoxy-12-hydroxyoctadecanoate + ?
73.6% yield
-
-
?
1.11.2.3
styrene + tert-butyl hydroperoxide
-
712776
Avena sativa
epoxyethyl benzene + ?
57.4% yield
-
-
?
1.11.2.3
trans-2-heptene + tert-butyl hydroperoxide
-
712776
Avena sativa
2-butyl-3-methyl-trans-oxirane + ?
26.6% yield
-
-
?
Cofactor
EC Number
Cofactor
Commentary
Organism
Structure
1.11.2.3
heme
-
Avena sativa
Cofactor (protein specific)
EC Number
Cofactor
Commentary
Organism
Structure
1.11.2.3
heme
-
Avena sativa
Localization (protein specific)
EC Number
Localization
Commentary
Organism
GeneOntology No.
Textmining
1.11.2.3
membrane
-
Avena sativa
16020
-
Source Tissue (protein specific)
EC Number
Source Tissue
Commentary
Organism
Textmining
1.11.2.3
seed
-
Avena sativa
-
Substrates and Products (Substrate) (protein specific)
EC Number
Substrates
Commentary Substrates
Literature (Substrates)
Organism
Products
Commentary (Products)
Literature (Products)
Organism (Products)
Reversibility
1.11.2.3
2-methylhept-1-ene + tert-butyl hydroperoxide
-
712776
Avena sativa
2-methyl-2-pentyloxirane + ?
-
-
-
?
1.11.2.3
cis-2-heptene + tert-butyl hydroperoxide
-
712776
Avena sativa
2-butyl-3-methyl-cis-oxirane + ?
93.9% yield
-
-
?
1.11.2.3
cis-3-heptene + tert-butyl hydroperoxide
-
712776
Avena sativa
2-ethyl-3-propyl-cis-oxirane + ?
72.7% yield
-
-
?
1.11.2.3
cyclohexene + tert-butyl hydroperoxide
-
712776
Avena sativa
7-oxabicyclo-[4.1.0]-heptane + ?
70.5% yield
-
-
?
1.11.2.3
hept-1-ene + tert-butyl hydroperoxide
-
712776
Avena sativa
2-pentyloxirane + ?
2.8% yield
-
-
?
1.11.2.3
linoleate + tert-butyl hydroperoxide
-
712776
Avena sativa
(9Z)-12,13-epoxyoctadec-9-enoate + (12Z)-9,10-epoxyoctadec-12-enoate + 9,10-12,13-diepoxy-octadecanoate + ?
23.4% yield, 25.4% yield and 46.7% yield, respectively
-
-
?
1.11.2.3
linoleate methyl ester + tert-butyl hydroperoxide
-
712776
Avena sativa
methyl 12,13-epoxy-9(Z)-octadecenoate + methyl 9,10-epoxy-12(Z)-octadecenoate + methyl 9,10-12,13-diepoxyoctadecanoate + ?
17.6% yield, 21.9% yield and 49.5% yield, respectively
-
-
?
1.11.2.3
linolenate + tert-butyl hydroperoxide
-
712776
Avena sativa
additional information
0.6% monoepoxy product and 91.6% diepoxy product
-
-
?
1.11.2.3
methyl (13Z)-docos-13-enoate + tert-butyl hydroperoxide
-
712776
Avena sativa
methyl behenate 13,14-epoxide + H2O
26.9% yield
-
-
?
1.11.2.3
methyl linolenate + tert-butyl hydroperoxide
-
712776
Avena sativa
additional information
14.3% monoepoxy product and 78.3% diepoxy product
-
-
?
1.11.2.3
oleate + tert-butyl hydroperoxide
-
712776
Avena sativa
methyl 9,10-epoxyoctadecanoate + ?
99.8% yield
-
-
?
1.11.2.3
oleate methyl ester + tert-butyl hydroperoxide
-
712776
Avena sativa
methyl 9,10-epoxyoctadecanoate + ?
93.9% yield
-
-
?
1.11.2.3
ricinoleate + tert-butyl hydroperoxide
-
712776
Avena sativa
9,10-epoxy-12-hydroxyoctadecanoate + ?
73.6% yield
-
-
?
1.11.2.3
styrene + tert-butyl hydroperoxide
-
712776
Avena sativa
epoxyethyl benzene + ?
57.4% yield
-
-
?
1.11.2.3
trans-2-heptene + tert-butyl hydroperoxide
-
712776
Avena sativa
2-butyl-3-methyl-trans-oxirane + ?
26.6% yield
-
-
?