BRENDA - Enzyme Database show

One-pot synthesis of fatty acid epoxides from triacylglycerols using enzymes present in oat seeds

Piazza, G.J.; Foglia, T.A.; J. Am. Oil Chem. Soc. 83, 1021-1025 (2006)

Data extracted from this reference:

Metals/Ions
EC Number
Metals/Ions
Commentary
Organism
Structure
1.11.2.3
additional information
peroxygenase activity is not stimulated by Ca2+
Avena sativa
Natural Substrates/ Products (Substrates)
EC Number
Natural Substrates
Organism
Commentary (Nat. Sub.)
Natural Products
Commentary (Nat. Pro.)
Organism (Nat. Pro.)
Reversibility
1.11.2.3
(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + tert-butyl hydroperoxide
Avena sativa
-
(12Z,15Z)-9,10-epoxyoctadeca-12,15-dienoic aicd + (9Z,12Z)-15,16-epoxy-9,12-octadecadienoic acid + ?
-
-
?
1.11.2.3
2 linolenic acid + 3 tert-butyl hydroperoxide
Avena sativa
-
(12Z,15Z)-9-epoxyoctadec-12,15-dienoic acid + (12Z)-9,15-diepoxyoctadec-12-enoic acid + 3 tert-butanol
-
-
?
1.11.2.3
linoleic acid + tert-butyl hydroperoxide
Avena sativa
-
9,10-epoxy-octadecanoic acid + tert-butanol
-
-
?
1.11.2.3
additional information
Avena sativa
the enzyme does not oxidize diacylglycerol and triacylglycerol
?
-
-
-
Organism
EC Number
Organism
Primary Accession No. (UniProt)
Commentary
Textmining
1.11.2.3
Avena sativa
-
-
-
Source Tissue
EC Number
Source Tissue
Commentary
Organism
Textmining
1.11.2.3
seed
-
Avena sativa
-
Substrates and Products (Substrate)
EC Number
Substrates
Commentary Substrates
Literature (Substrates)
Organism
Products
Commentary (Products)
Literature (Products)
Organism (Products)
Reversibility
1.11.2.3
(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + tert-butyl hydroperoxide
-
712256
Avena sativa
(12Z,15Z)-9,10-epoxyoctadeca-12,15-dienoic aicd + (9Z,12Z)-15,16-epoxy-9,12-octadecadienoic acid + ?
-
-
-
?
1.11.2.3
2 linolenic acid + 3 tert-butyl hydroperoxide
-
712256
Avena sativa
(12Z,15Z)-9-epoxyoctadec-12,15-dienoic acid + (12Z)-9,15-diepoxyoctadec-12-enoic acid + 3 tert-butanol
-
-
-
?
1.11.2.3
linoleic acid + tert-butyl hydroperoxide
-
712256
Avena sativa
9,10-epoxy-octadecanoic acid + tert-butanol
-
-
-
?
1.11.2.3
additional information
the enzyme does not oxidize diacylglycerol and triacylglycerol
712256
Avena sativa
?
-
-
-
-
pH Optimum
EC Number
pH Optimum Minimum
pH Optimum Maximum
Commentary
Organism
1.11.2.3
6
7
-
Avena sativa
Metals/Ions (protein specific)
EC Number
Metals/Ions
Commentary
Organism
Structure
1.11.2.3
additional information
peroxygenase activity is not stimulated by Ca2+
Avena sativa
Natural Substrates/ Products (Substrates) (protein specific)
EC Number
Natural Substrates
Organism
Commentary (Nat. Sub.)
Natural Products
Commentary (Nat. Pro.)
Organism (Nat. Pro.)
Reversibility
1.11.2.3
(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + tert-butyl hydroperoxide
Avena sativa
-
(12Z,15Z)-9,10-epoxyoctadeca-12,15-dienoic aicd + (9Z,12Z)-15,16-epoxy-9,12-octadecadienoic acid + ?
-
-
?
1.11.2.3
2 linolenic acid + 3 tert-butyl hydroperoxide
Avena sativa
-
(12Z,15Z)-9-epoxyoctadec-12,15-dienoic acid + (12Z)-9,15-diepoxyoctadec-12-enoic acid + 3 tert-butanol
-
-
?
1.11.2.3
linoleic acid + tert-butyl hydroperoxide
Avena sativa
-
9,10-epoxy-octadecanoic acid + tert-butanol
-
-
?
1.11.2.3
additional information
Avena sativa
the enzyme does not oxidize diacylglycerol and triacylglycerol
?
-
-
-
Source Tissue (protein specific)
EC Number
Source Tissue
Commentary
Organism
Textmining
1.11.2.3
seed
-
Avena sativa
-
Substrates and Products (Substrate) (protein specific)
EC Number
Substrates
Commentary Substrates
Literature (Substrates)
Organism
Products
Commentary (Products)
Literature (Products)
Organism (Products)
Reversibility
1.11.2.3
(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + tert-butyl hydroperoxide
-
712256
Avena sativa
(12Z,15Z)-9,10-epoxyoctadeca-12,15-dienoic aicd + (9Z,12Z)-15,16-epoxy-9,12-octadecadienoic acid + ?
-
-
-
?
1.11.2.3
2 linolenic acid + 3 tert-butyl hydroperoxide
-
712256
Avena sativa
(12Z,15Z)-9-epoxyoctadec-12,15-dienoic acid + (12Z)-9,15-diepoxyoctadec-12-enoic acid + 3 tert-butanol
-
-
-
?
1.11.2.3
linoleic acid + tert-butyl hydroperoxide
-
712256
Avena sativa
9,10-epoxy-octadecanoic acid + tert-butanol
-
-
-
?
1.11.2.3
additional information
the enzyme does not oxidize diacylglycerol and triacylglycerol
712256
Avena sativa
?
-
-
-
-
pH Optimum (protein specific)
EC Number
pH Optimum Minimum
pH Optimum Maximum
Commentary
Organism
1.11.2.3
6
7
-
Avena sativa