Literature summary extracted from

Crombie, L.; Morgan, D.O.; Smith, E.H.
The enzymic formation of colneleic acid, a divinyl ether fatty acid: experiments with [(9S)-18O2]hydroperoxyoctadeca-(10E),(12Z)-dienoic acid (1987), J. Chem. Soc. Chem. Commun., 1987, 502-503.

No PubMed abstract available

Organism

EC Number	Organism	UniProt	Comment	Textmining
4.2.1.121	Solanum tuberosum	-	-	-

Reaction

EC Number	Reaction	Comment	Organism	Reaction ID
4.2.1.121	(9S,10E,12Z)-9-hydroperoxyoctadeca-10,12-dienoate = (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoate + H2O	the oxygen inserted enzymically between carbons 9- and 10- of the C-18 chain in forming colneleic acid originates from 18O2 gas via the hydroperoxide group of linoleic acid. A mechanism is proposed	Solanum tuberosum	a

Source Tissue

EC Number	Source Tissue	Comment	Organism	Textmining
4.2.1.121	tuber	-	Solanum tuberosum	-

Substrates and Products (Substrate)

EC Number	Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
4.2.1.121	(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate	-	Solanum tuberosum	(8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoic acid + H2O	i.e. colneleate	?

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Release 2023.1 (January 2023)