EC Number | Organism | UniProt | Comment | Textmining |
---|---|---|---|---|
5.5.1.8 | Salvia officinalis | O81192 | - |
- |
EC Number | Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|---|
5.5.1.8 | geranyl diphosphate | - |
Salvia officinalis | (+)-bornyl diphosphate | - |
? | |
5.5.1.8 | additional information | the reaction mechanism in BPPS involves the following steps: binding of geranyl diphospahte, metal-activated ionization to yield an allylic transoid carbocation, formation of (3R)-linalyl diphosphate, rotation around the C2-C3 bond and ionization to generate a cisoid allylic cation in the reactive conformation, cyclization to form a (4R)-R-terpinyl cation, further cyclization to yield (+)-2-bornyl cation, and reincorporation of the diphosphate by the (+)-2-bornyl carbocation, to yield the final product (+)-bornyl diphosphate in ca. 75% yield | Salvia officinalis | ? | - |
? |
EC Number | Synonyms | Comment | Organism |
---|---|---|---|
5.5.1.8 | (+)-bornyl diphosphate synthase | - |
Salvia officinalis |
5.5.1.8 | BPPS | - |
Salvia officinalis |