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Literature summary extracted from

  • Hajdok, S.; Conrad, J.; Leutbecher, H.; Strobel, S.; Schleid, T.; Beifuss, U.
    The laccase-catalyzed domino reaction between catechols and heterocyclic 1,3-dicarbonyls and the unambiguous structure elucidation of the products by NMR spectroscopy and X-ray crystal structure analysis (2009), J. Org. Chem., 74, 7230-7237.
    View publication on PubMed

Organism

EC Number Organism UniProt Comment Textmining
1.10.3.2 Agaricus bisporus
-
-
-

Reaction

EC Number Reaction Comment Organism Reaction ID
1.10.3.2 4 benzenediol + O2 = 4 benzosemiquinone + 2 H2O catalytic reaction mechanism, modelling, overview Agaricus bisporus
a

Source Tissue

EC Number Source Tissue Comment Organism Textmining
1.10.3.2 commercial preparation
-
 Agaricus bisporus
-

Specific Activity [micromol/min/mg]

EC Number Specific Activity Minimum [µmol/min/mg] Specific Activity Maximum [µmol/min/mg] Comment Organism
1.10.3.2 156
-
-
 Agaricus bisporus

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.10.3.2 (4a'S)-2',3',6',7'-tetrahydroxy-1,1'',3,3''-tetramethyl-4a',9a'-dihydro-2H,2''H-dispiro[pyrimidine-5,9'-anthracene-10',5''-pyrimidine]-2,2'',4,4'',6,6''(1H,1''H,3H,3''H)-hexone + O2
-
 Agaricus bisporus 2',3',6',7'-tetrahydroxy-1,1'',3,3''-tetramethyldispiro[pyrimidine-5(2H),9'(10'H)-anthracene-10',5''(2''H)-pyrimidine]-2,2'',4,4'',6,6''-(1H,1''H,3H,3''H)-hexone + H2O2 a polycyclic dispiropyrimidinone ?
1.10.3.2 2 catechol + O2
-
 Agaricus bisporus 2 o-quinone + 2 H2O
-
 ?
1.10.3.2 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic) acid + O2
-
 Agaricus bisporus ?
-
 ?
1.10.3.2 4-hydroxy-1,6-dimethylpyridin-2(1H)-one + 3-methoxy-1,2-benzenediol
-
 Agaricus bisporus 7,8-dihydroxy-6-methoxy-2,3-dimethylbenzofuro[3,2-c]pyridin-1(2H)-one
-
 ?
1.10.3.2 4-hydroxy-1,6-dimethylpyridin-2(1H)-one + 3-methyl-1,2-benzenediol
-
 Agaricus bisporus 7,8-dihydroxy-2,3,6-trimethyl[1]benzofuro[3,2-c]pyridin-1(2H)-one
-
 ?
1.10.3.2 4-hydroxy-1,6-dimethylpyridin-2(1H)-one + benzenediol
-
 Agaricus bisporus 7,8-dihydroxy-2,3-dimethyl[1]benzofuro[3,2-c]pyridin-1(2H)-one
-
 ?
1.10.3.2 4-hydroxy-1-thiocoumarin + 3-methoxy-1,2-benzenediol
-
 Agaricus bisporus 8,9-dihydroxy-10-methoxy-6H-thiochromeno[4,3-b][1]benzofuran-6-one
-
 ?
1.10.3.2 4-hydroxy-1-thiocoumarin + 3-methyl-1,2-benzenediol
-
 Agaricus bisporus 8,9-dihydroxy-10-methyl-6H-thiochromeno[4,3-b][1]benzofuran-6-one
-
 ?
1.10.3.2 4-hydroxy-1-thiocoumarin + benzenediol
-
 Agaricus bisporus 8,9-dihydroxy-6H-thiochromeno[4,3-b][1]benzofuran-6-one
-
 ?
1.10.3.2 4-hydroxy-6-methylpyridin-2(1H)-one + 3-methoxy-1,2-benzenediol
-
 Agaricus bisporus 7,8-dihydroxy-6-methoxy-3-methyl[1]benzofuro[3,2-c]pyridin-1(2H)-one
-
 ?
1.10.3.2 4-hydroxy-6-methylpyridin-2(1H)-one + 3-methyl-1,2-benzenediol
-
 Agaricus bisporus 7,8-dihydroxy-3,6-dimethyl[1]benzofuro[3,2-c]pyridin-1(2H)-one
-
 ?
1.10.3.2 4-hydroxy-6-methylpyridin-2(1H)-one + benzenediol
-
 Agaricus bisporus 7,8-dihydroxy-3-methyl[1]benzofuro[3,2-c]pyridin-1(2H)-one
-
 ?
1.10.3.2 4-hydroxyquinolin-2(1H)-one + 3-methoxy-1,2-benzenediol
-
 Agaricus bisporus 8,9-dihydroxy-10-methoxy[1]benzofuro[3,2-c]quinolin-6(5H)-one
-
 ?
1.10.3.2 4-hydroxyquinolin-2(1H)-one + 3-methyl-1,2-benzenediol
-
 Agaricus bisporus 8,9-dihydroxy-10-methyl[1]benzofuro[3,2-c]quinolin-6(5H)-one
-
 ?
1.10.3.2 4-hydroxyquinolin-2(1H)-one + benzenediol
-
 Agaricus bisporus 8,9-dihydroxy[1]benzofuro[3,2-c]quinolin-6(5H)-one
-
 ?
1.10.3.2 benzenediol + thiobarbituric acid
-
 Agaricus bisporus 1,1'',3,3''-tetraethyl-2',3',6',7'-tetrahydroxy-2,2''-dithioxo-2H,2''H-dispiro[pyrimidine-5,9'-anthracene-10',5''-pyrimidine]-4,4'',6,6''(1H,1''H,3H,3''H)-tetrone
-
 ?
1.10.3.2 N,N-dimethylbarbituric acid + catechol
-
 Agaricus bisporus 2',3',6',7'-tetrahydroxy-1,1'',3,3''-tetramethyldispiro[pyrimidine-5(2H),9'(10'H)-anthracene-10',5''(2''H)-pyrimidine]-2,2'',4,4'',6,6''-(1H,1''H,3H,3''H)-hexone a polycyclic dispiropyrimidinone ?
1.10.3.2 o-quinone + N,N-dimethylbarbituric acid
-
 Agaricus bisporus ?
-
 ?

Synonyms

EC Number Synonyms Comment Organism
1.10.3.2 benzenediol:O2 oxidoreductase
-
 Agaricus bisporus

Temperature Optimum [°C]

EC Number Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
1.10.3.2 25
-
 assay at Agaricus bisporus

pH Optimum

EC Number pH Optimum Minimum pH Optimum Maximum Comment Organism
1.10.3.2 6
-
 assay at Agaricus bisporus