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Literature summary extracted from

  • Balogh-Hergovich, E.; Kaizer, J.; Speier, G.
    Copper mediated conversion of nitro compounds to aldehydes or ketones by dioxygen (1996), Chem. Lett., 25, 573-574.
No PubMed abstract available

Organism

EC Number Organism UniProt Comment Textmining
1.13.12.16 Cyberlindnera mrakii
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Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.13.12.16 2-nitro-1H-indene-1,3(2H)-dione + Cu(0) + N,N,N',N'-tetramethylethylenediamine + O2 with N,N-dimethylformamid (conversion: 30%) as solvent Cyberlindnera mrakii 1H-indene-1,2,3,-trione + (NO2)CuN,N,N',N'-tetramethylethylenediamine
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 ?
1.13.12.16 ethylnitronate + Cu(0) + N,N,N',N'-tetramethylethylenediamine + O2 with N,N-dimethylformamid (conversion: 60%) and pyridine (conversion: 90%) as solvent Cyberlindnera mrakii acetone + (NO2)CuN,N,N',N'-tetramethylethylenediamine
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 ?
1.13.12.16 pentane-1-nitronate + Cu(0) + N,N,N',N'-tetramethylethylenediamine + O2 with N,N-dimethylformamid (conversion: 28%) and pyridine (conversion: 21%) as solvent Cyberlindnera mrakii pentaldehyde + (NO2)CuN,N,N',N'-tetramethylethylenediamine
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 ?
1.13.12.16 propyl-2-nitronate + Cu(0) + 1,10-phenanthroline + O2 with methanol (conversion: 42%), MeCN (conversion: 24%), and N,N-dimethylformamid (conversion: 43%) Cyberlindnera mrakii propan-2-one + ?
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 ?
1.13.12.16 propyl-2-nitronate + Cu(0) + 2,2'-bipyridine + O2 with methanol (conversion: 44%), MeCN (conversion: 54%), and N,N-dimethylformamid (conversion: 37%) Cyberlindnera mrakii propan-2-one + ?
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 ?
1.13.12.16 propyl-2-nitronate + Cu(0) + N,N,N',N'-tetramethylethylenediamine + O2 with methanol (conversion: 70%), MeCN (conversion: 49%), N,N-dimethylformamid (conversion: 71%), and pyridine (conversion: 67%) as solvent Cyberlindnera mrakii propan-2-one + (NO2)CuN,N,N',N'-tetramethylethylenediamine
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1.13.12.16 propyl-2-nitronate + Cu(0) + O2 without ligand and without solvent (conversion: 12%) Cyberlindnera mrakii propan-2-one + ?
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1.13.12.16 undecan-6-nitronate + Cu(0) + N,N,N',N'-tetramethylethylenediamine + O2 with N,N-dimethylformamid (conversion: 66%) and pyridine (conversion: 67%) as solvent Cyberlindnera mrakii undecan-6-one + (NO2)CuN,N,N',N'-tetramethylethylenediamine
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