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Literature summary extracted from

  • Lindborg, J.; Tanskanen, A.; Kanerva, L.
    Chemoselective chloroperoxidase-catalyzed oxidation of hexen-1-ols (2009), Biocatal. Biotransform., 27, 204-210.
No PubMed abstract available

Application

EC Number Application Comment Organism
1.11.1.10 synthesis oxidation of hexen-1-ols with tert-butyl hydroperoxide Leptoxyphium fumago

Organism

EC Number Organism UniProt Comment Textmining
1.11.1.10 Leptoxyphium fumago
-
-
-

Purification (Commentary)

EC Number Purification (Comment) Organism
1.11.1.10
-
 Leptoxyphium fumago

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.11.1.10 (2E)-hex-2-en-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago trans-(3-propyloxiran-2-yl)methanol + H2O
-
 ?
1.11.1.10 (2Z)-hex-2-en-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago cis-(3-propyloxiran-2-yl)methanol + H2O
-
 ?
1.11.1.10 (2Z)-pent-2-en-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago cis-2-(3-ethyloxiran-2-yl)ethanol + (3Z)-hex-3-enal + H2O
-
 ?
1.11.1.10 (4Z)-hex-4-en-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago 3-(3-methyloxiran-2-yl)propan-1-ol + (4Z)-hex-4-enal + H2O
-
 ?
1.11.1.10 5-hexen-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago 5-hexenal + ? only a small amount is produced ?
1.11.1.10 5-hexen-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago hex-5-enal + H2O
-
 ?
1.11.1.10 cis-2-hexen-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago cis-2-hexenal + ? further production of small amounts of trans-2-hexenal, cis-3-hexenal and trans-3-hexenal ?
1.11.1.10 cis-3-hexen-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago cis-3-hexenal + ? further production of small amounts of cis-2-hexenal, trans-2-hexenal and trans-3-hexenal ?
1.11.1.10 cis-4-hexen-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago cis-4-hexenal + cis-4,5-epoxyhexan-1-ol + ? further production of small amounts of trans-4,5-epoxyhexan-1-ol and trans-4-hexenal ?
1.11.1.10 trans-2-hexen-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago trans-2-hexenal + ? further production of small amounts of cis-2-hexenal,cis-3-hexenal and trans-3-hexenal ?
1.11.1.10 trans-3-hexen-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago trans-3-hexenal + ? further production of small amounts of cis-3-hexenal, trans-2-hexenal and cis-3-hexenal ?
1.11.1.10 trans-4-hexen-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago trans-4-hexenal + trans-4,5-epoxyhexan-1-ol + ? further production of small amounts of cis-4,5-epoxyhexan-1-ol and cis-4-hexenal ?
1.11.1.10 trans-4-hexen-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago trans-2-(3-ethyloxiran-2-yl)ethanol + (3E)-hex-3-enal + H2O
-
 ?
1.11.1.10 trans-4-hexen-1-ol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago trans-4,5-epoxyhexan-1-ol + trans-4-hexenal + H2O + ?
-
 ?

Synonyms

EC Number Synonyms Comment Organism
1.11.1.10 chloroperoxidase
-
 Leptoxyphium fumago
1.11.1.10 CPO
-
 Leptoxyphium fumago

Cofactor

EC Number Cofactor Comment Organism Structure
1.11.1.10 heme
-
 Leptoxyphium fumago