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Literature summary extracted from

  • Hwang, S.; Choi, C.Y.; Lee, E.Y.
    Enantioconvergent bioconversion of p-chlorostyrene oxide to (R)-p-chlorophenyl-1,2-ethandiol by the bacterial epoxide hydrolase of Caulobacter crescentus (2008), Biotechnol. Lett., 30, 1219-1225.
    View publication on PubMed

Application

EC Number Application Comment Organism
3.3.2.10 synthesis enantioselective hydrolysis of racemic styrene derivative via attack of the benzylic position results in formation of the correspponding (R)-diol with enantiomeric excess of up to 96% and more than 90% conversion Caulobacter vibrioides

Cloned(Commentary)

EC Number Cloned (Comment) Organism
3.3.2.10 expression in Escherichia coli Caulobacter vibrioides

Organism

EC Number Organism UniProt Comment Textmining
3.3.2.10 Caulobacter vibrioides
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
3.3.2.10 4-chlorostyrene oxide + H2O
-
 Caulobacter vibrioides (1R)-1-(4-chlorophenyl)ethane-1,2-diol conversion of racemic substrate via attack of the benzylic position to R-diol with 96% enantiomeric excess ?
3.3.2.10 4-nitrostyrene oxide + H2O
-
 Caulobacter vibrioides (1R)-1-(4-nitrophenyl)ethane-1,2-diol conversion of racemic substrate via attack of the benzylic position to R-diol with 80% enantiomeric excess ?
3.3.2.10 styrene oxide + H2O
-
 Caulobacter vibrioides (1R)-1-phenylethane-1,2-diol conversion of racemic substrate via attack of the benzylic position to R-diol with 90% enantiomeric excess ?