BRENDA - Enzyme Database

Monoterpenes as novel substrates for oxidation and halo-hydroxylation with chloroperoxidase from Caldariomyces fumago

Kaup, B.A.; Piantini, U.; Wuest, M.; Schrader, J.; Appl. Microbiol. Biotechnol. 73, 1087-1096 (2007) View publication on PubMed

Data extracted from this reference:

Organism
EC Number
Organism
UniProt
Commentary
Textmining
1.11.1.10
Leptoxyphium fumago
-
-
-
Substrates and Products (Substrate)
EC Number
Substrates
Commentary Substrates
Literature (Substrates)
Organism
Products
Commentary (Products)
Literature (Products)
Organism (Products)
Reversibility
Substrate Product ID
1.11.1.10
(+/-)-citronellol + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
(+/-)-linalool + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
(-)-alpha-pinene + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
(-)-beta-pinene + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
(1S)-3-carene + Cl- + H2O2
-
671543
Leptoxyphium fumago
(1S,3R,4R,6R)-4-chloro-3,7,7-trimethyl-bicyclo[4.1.0]heptane-3-ol + H2O
-
-
-
?
1.11.1.10
(R)-limonene + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
(Z)-beta-ocimene + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
beta-myrcene + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
geraniol + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
additional information
in the presence of enzyme and H2O2, but in the absence of chloride or bromide, the terpene alcohols geraniol, nerol and citronellol are substrates of CPO and are oxidized to the corresponding aldehydes geranial, neral and citronellal, respectively
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
nerol + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
Cofactor
EC Number
Cofactor
Commentary
Organism
Structure
1.11.1.10
heme
-
Leptoxyphium fumago
Cofactor (protein specific)
EC Number
Cofactor
Commentary
Organism
Structure
1.11.1.10
heme
-
Leptoxyphium fumago
Substrates and Products (Substrate) (protein specific)
EC Number
Substrates
Commentary Substrates
Literature (Substrates)
Organism
Products
Commentary (Products)
Literature (Products)
Organism (Products)
Reversibility
ID
1.11.1.10
(+/-)-citronellol + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
(+/-)-linalool + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
(-)-alpha-pinene + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
(-)-beta-pinene + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
(1S)-3-carene + Cl- + H2O2
-
671543
Leptoxyphium fumago
(1S,3R,4R,6R)-4-chloro-3,7,7-trimethyl-bicyclo[4.1.0]heptane-3-ol + H2O
-
-
-
?
1.11.1.10
(R)-limonene + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
(Z)-beta-ocimene + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
beta-myrcene + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
geraniol + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
additional information
in the presence of enzyme and H2O2, but in the absence of chloride or bromide, the terpene alcohols geraniol, nerol and citronellol are substrates of CPO and are oxidized to the corresponding aldehydes geranial, neral and citronellal, respectively
671543
Leptoxyphium fumago
?
-
-
-
?
1.11.1.10
nerol + Cl- + H2O2
-
671543
Leptoxyphium fumago
?
-
-
-
?