Any feedback?
Please rate this page
(literature.php)
(0/150)

BRENDA support

Literature summary extracted from

  • Cabirol, F.L.; Hanefeld, U.; Sheldon, R.A.
    Immobilized hydroxynitrile lyases for enantioselective synthesis of cyanohydrins: sol-gels and cross-linked enzyme aggregates (2006), Adv. Synth. Catal., 348, 1645-1654.
No PubMed abstract available

Organism

EC Number Organism UniProt Comment Textmining
4.1.2.47 Hevea brasiliensis
-
 precipitated hydroxynitrile lyase, comparison of free, cross-linked enzyme aggregate (CLEA) and immobilized in sol-gel (aqua gel)
-

Purification (Commentary)

EC Number Purification (Comment) Organism
4.1.2.47 preparation of a cross-linked enzyme aggregate (CLEA) from hydroxynitrile lyase from Hevea brasiliensis, precipitated hydroxynitrile lyase, comparison of free, cross-linked enzyme aggregate (CLEA) and immobilized in sol-gel (aqua gel) Hevea brasiliensis

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.1.2.47 2-furaldehyde cyanohydrin aqua gel, 30 min, conversion ratio: 89%, enantiomeric excess: 94% Hevea brasiliensis 2-furaldehyde + HCN
-
 r
4.1.2.47 2-furaldehyde cyanohydrin free enzyme, 30 min, conversion ratio: 89%,enantiomeric excess: 94% Hevea brasiliensis 2-furaldehyde + HCN
-
 r
4.1.2.47 hexanal cyanohydrin aqua gel, 2 h, conversion ratio: 92%, enantiomeric excess: 94% Hevea brasiliensis hexanal + HCN
-
 r
4.1.2.47 hexanal cyanohydrin free enzyme, 4 h, conversion ratio: 91%,enantiomeric excess: 94% Hevea brasiliensis hexanal + HCN
-
 r
4.1.2.47 m-phenoxybenzaldehyde cyanohydrin aqua gel, 72 h, conversion ratio: 92%, enantiomeric excess: 98% Hevea brasiliensis m-phenoxybenzaldehyde + HCN
-
 r
4.1.2.47 m-phenoxybenzaldehyde cyanohydrin free enzyme, 72 h, conversion ratio: 45%,enantiomeric excess: 82% Hevea brasiliensis m-phenoxybenzaldehyde + HCN
-
 r
4.1.2.47 mandelonitrile aqua gel, 0.5 h, conversion ratio: 97%, enantiomeric excess: 99% Hevea brasiliensis benzaldehyde + HCN
-
 r
4.1.2.47 mandelonitrile CLEA, 72 h, conversion ratio: 55%, enantiomeric excess: 67% Hevea brasiliensis benzaldehyde + HCN
-
 r
4.1.2.47 mandelonitrile free enzyme, 4 h, conversion ratio: 97%,enantiomeric excess: 97% Hevea brasiliensis benzaldehyde + HCN
-
 r

Synonyms

EC Number Synonyms Comment Organism
4.1.2.47 (S)-HbHNL
-
 Hevea brasiliensis
4.1.2.47 HbHNL
-
 Hevea brasiliensis
4.1.2.47 Hydroxynitrile lyase
-
 Hevea brasiliensis
4.1.2.47 Oxynitrilase
-
 Hevea brasiliensis