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Literature summary extracted from

  • Hatzakis, N.S.; Daphnomili, D.; Smonou, I.
    Ferulic acid esterase from Humicola Insolens catalyzes enantioselective transesterification of secondary alcohols (2003), J. Mol. Catal. B, 21, 309-311.
No PubMed abstract available

Application

EC Number Application Comment Organism
3.1.1.73 synthesis potential for the production of ferulic acid as antioxidant, food preservative, anti-inflammatory and antitumor agent, photoprotectant or flavor precursor Humicola insolens

Localization

EC Number Localization Comment Organism GeneOntology No. Textmining
3.1.1.73 extracellular
-
Humicola insolens
-
-

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
3.1.1.73 feruloyl polysaccharide + H2O Humicola insolens involved in the degradation of plant cell wall material, breaks ferulic acid cross-links between cell wall components ferulic acid + ? monomeric and 5,5’ dimeric forms released from insoluble plant cell wall material ?

Organism

EC Number Organism UniProt Comment Textmining
3.1.1.73 Humicola insolens
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
3.1.1.73 1-(1,1'-biphenyl)-4-yl-1-ethanol + vinyl acetate transesterification, 17% conversion with a 30-fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
3.1.1.73 1-(3-methylphenyl)-1-ethanol + vinyl acetate transesterification, 52% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
3.1.1.73 1-(4-isopropylphenyl)-1-ethanol + vinyl acetate transesterification, 7% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
3.1.1.73 1-(4-methoxyphenyl)-1-ethanol + vinyl acetate transesterification, 18% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
3.1.1.73 1-(4-pyridinyl)-1-ethanol + vinyl acetate transesterification, 50% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens 1-pyridin-4-ylethylacetate + prop-2-en-1-ol
-
?
3.1.1.73 1-phenyl-1-ethanol + vinyl acetate transesterification, 23% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
3.1.1.73 1-phenyl-1-propanol + vinyl acetate transesterification, 25% conversion with a 30fold excess of vinyl acetate, high enantioselectivity with R enantiopreference Humicola insolens ?
-
?
3.1.1.73 feruloyl polysaccharide + H2O involved in the degradation of plant cell wall material, breaks ferulic acid cross-links between cell wall components Humicola insolens ferulic acid + ? monomeric and 5,5’ dimeric forms released from insoluble plant cell wall material ?