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Literature summary extracted from

  • Wu, W.B.; Wang, N.; Xu, J.M.; Wu, Q.; Lin, X.F.
    Penicillin G acylase catalyzed Markovnikov addition of allopurinol to vinyl ester (2005), Chem. Commun. (Camb.), 2005, 2348-2350.
    View publication on PubMed

Application

EC Number Application Comment Organism
3.5.1.11 synthesis Markovnikov addition of allopurinol to vinyl ester by enzyme immobilized on acrylic beads. With vinyl acetate in dimethylsulfoxide, yield is about 60%. Decrease in activity in the order vinyl acetate, vinyl pentanoate, vinyl decanoate. Divinyl dicarboxylate reacts faster than the comparable mono-acid vinyl ester Escherichia coli

Organism

EC Number Organism UniProt Comment Textmining
3.5.1.11 Escherichia coli
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Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
3.5.1.11 allopurinol + vinyl acetate Markovnikov addition, decrease in activity in the order vinyl acetate, vinyl pentanoate, vinyl decanoate Escherichia coli 1-(4-oxo-4,5-dihydro-1H-pyrazolo[3,4-d]pyrimidin-1-yl)ethyl acetate
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 ?
3.5.1.11 allopurinol + vinyl decanoate Markovnikov addition, decrease in activity in the order vinyl acetate, vinyl pentanoate, vinyl decanoate Escherichia coli 1-(4-oxo-4,5-dihydro-1H-pyrazolo[3,4-d]pyrimidin-1-yl)ethyl decanoate
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 ?
3.5.1.11 allopurinol + vinyl pentanoate Markovnikov addition, decrease in activity in the order vinyl acetate, vinyl pentanoate, vinyl decanoate Escherichia coli 1-(4-oxo-4,5-dihydro-1H-pyrazolo[3,4-d]pyrimidin-1-yl)ethyl pentanoate
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 ?