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Literature summary extracted from

  • Bougioukou, D.J.; Smonou, I.
    Chloroperoxidase-catalyzed oxidation of conjugated dienoic esters (2002), Tetrahedron Lett., 43, 339-342.
No PubMed abstract available

Organism

EC Number Organism UniProt Comment Textmining
1.11.1.10 Leptoxyphium fumago
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-
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Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.11.1.10 (3E,5E)-hepta-3,5-dien-2-one + tert-butyl hydroperoxide
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 Leptoxyphium fumago (2E,4E)-6-oxohepta-2,4-dienal + (3E)-4-(3-methyloxiran-2-yl)but-3-en-2-one + (2E)-4-oxopent-2-enal 83% (2E,4E)-6-oxohepta-2,4-dienal, 4% (3E)-4-(3-methyloxiran-2-yl)but-3-en-2-one, and 13% (2E)-4-oxopent-2-enal ?
1.11.1.10 (3Z,5E)-hepta-3,5-dien-2-one + tert-butyl hydroperoxide
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 Leptoxyphium fumago (2E,4Z)-6-oxohepta-2,4-dienal + (2E)-4-oxopent-2-enal + (2E,4E)-6-oxohepta-2,4-dienal 78% (2E,4Z)-6-oxohepta-2,4-dienal, 15% (2E)-4-oxopent-2-enal and 7% (2E,4E)-6-oxohepta-2,4-dienal ?
1.11.1.10 (3Z,5Z)-hepta-3,5-dien-2-one + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (2E,4Z)-6-oxohepta-2,4-dienal + (2E)-4-oxopent-2-enal + (3Z)-4-[(2S,3S)-3-methyloxiran-2-yl]but-3-en-2-one 27% (2E,4Z)-6-oxohepta-2,4-dienal, 38% (3E)-4-(3-methyloxiran-2-yl)but-3-en-2-one and 35% (3Z)-4-[(2S,3S)-3-methyloxiran-2-yl]but-3-en-2-one ?
1.11.1.10 additional information in halide-independent oxidation reactions, CPO uses H2O2 or other organic peroxides as the source of oxygen without requiring cofactors Leptoxyphium fumago ?
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 ?

Synonyms

EC Number Synonyms Comment Organism
1.11.1.10 chloroperoxidase
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 Leptoxyphium fumago
1.11.1.10 CPO
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 Leptoxyphium fumago