Any feedback?
Please rate this page
(literature.php)
(0/150)

BRENDA support

Literature summary extracted from

  • Hu, S.; Dordick, J.S.
    Highly enantioselective oxidation of cis-cyclopropylmethanols to corresponding aldehydes catalyzed by chloroperoxidase (2002), J. Org. Chem., 67, 314-317.
    View publication on PubMed

Organism

EC Number Organism UniProt Comment Textmining
1.11.1.10 Leptoxyphium fumago
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.11.1.10 (1R,2S)-(+)-2-benzylcyclopropylmethanol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (1S,2R)-(+)-2-benzyl-1-formylcyclopropane + ?
-
 ?
1.11.1.10 (1R,2S)-(+)-2-ethylcyclopropylmethanol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (1S,2R)-(-)-2-ethyl-1-formylcyclopropane + ?
-
 ?
1.11.1.10 (1R,2S)-(+)-2-methylcyclopropanemethanol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (1S,2R)-(-)-2-methyl-1-formylcyclopropane + ?
-
 ?
1.11.1.10 (1R,2S)-(+)-2-propylcyclopropylmethanol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (1S,2R)-(-)-1-formyl-2-propylcyclopropane + ?
-
 ?
1.11.1.10 (1R,2S)-(-)-2-acetoxymethylcyclopropylmethanol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (1S,2R)-2-acetoxymethyl-1-formylcyclopropane + ?
-
 ?
1.11.1.10 cis-2-phenylcyclopropylmethanol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago ?
-
 ?
1.11.1.10 trans-2-phenylcyclopropylmethanol + tert-butyl hydroperoxide formation of the aldehyde with poor enantioselectivity Leptoxyphium fumago ?
-
 ?
1.11.1.10 [2-(2-bromoethyl)cyclopropyl]methanol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago 2-(2-bromoethyl)cyclopropanecarbaldehyde + ?
-
 ?
1.11.1.10 [2-(3-bromopropyl)cyclopropyl]methanol + tert-butyl hydroperoxide
-
 Leptoxyphium fumago 2-(3-bromopropyl)cyclopropanecarbaldehyde + ?
-
 ?
1.11.1.10 [2-(hydroxymethyl)cyclopropyl]methyl acetate + tert-butyl hydroperoxide
-
 Leptoxyphium fumago (2-formylcyclopropyl)methyl acetate + ?
-
 ?