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Literature summary extracted from

  • Schwab, J.M.; Li, W.; Thomas, L.P.
    Cyclohexanone oxygenase: stereochemistry, enantioselectivity, and regioselectivity of an enzyme-catalyzed Baeyer-Villiger reaction (1983), J. Am. Chem. Soc., 105, 4800-4808.
No PubMed abstract available

Organism

EC Number Organism UniProt Comment Textmining
1.14.13.22 Acinetobacter sp.
-
 NCIB 9871
-

Purification (Commentary)

EC Number Purification (Comment) Organism
1.14.13.22
-
 Acinetobacter sp.

Reaction

EC Number Reaction Comment Organism Reaction ID
1.14.13.22 cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O stereochemistry Acinetobacter sp.
a
1.14.13.22 cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O mechanistic study Acinetobacter sp.
a
1.14.13.22 cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O enantioselectivity Acinetobacter sp.
a
1.14.13.22 cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O regioselectivity Acinetobacter sp.
a

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.14.13.22 2-methylcyclohexanone + NADPH + O2
-
 Acinetobacter sp. 1-oxa-2-oxo-3-methylcycloheptane + NADP+ + H2O
-
 ?
1.14.13.22 cyclohexanone + NADPH + O2
-
 Acinetobacter sp. 6-hexanolide + NADP+ + H2O
-
 ?

Cofactor

EC Number Cofactor Comment Organism Structure
1.14.13.22 NADPH
-
 Acinetobacter sp.