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Literature summary extracted from

  • Abril, O.; Ryerson, C.C.; Walsh, C.; Whitesides, G.M.
    Enzymatic Baeyer-Villiger type oxidations of ketones catalyzed by cyclohexanone oxygenase (1989), Bioorg. Chem., 17, 41-52.
No PubMed abstract available

Organism

EC Number Organism UniProt Comment Textmining
1.14.13.22 Acinetobacter sp.
-
 NCIB 9871
-

Reaction

EC Number Reaction Comment Organism Reaction ID
1.14.13.22 cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O general mechanistic scheme Acinetobacter sp.
a
1.14.13.22 cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O regioselectivity Acinetobacter sp.
a

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.14.13.22 (+)-camphor + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
1.14.13.22 (+)-dihydrocarvone + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
1.14.13.22 2-norbornanone + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
1.14.13.22 2-phenylcyclohexanone + NADPH + O2 slight Acinetobacter sp. 1-oxa-2-oxo-3-phenylcycloheptane + NADP+ + H2O
-
 ?
1.14.13.22 4-tert-butylcyclohexanone + NADPH + O2 slight Acinetobacter sp. 1-oxa-2-oxo-5-tert-butylcycloheptane + NADP+ + H2O
-
 ?
1.14.13.22 cyclohexan-1,4-dione + NADPH + O2
-
 Acinetobacter sp. 1-oxa-2,5-dioxo-cycloheptane + NADP+ + H2O
-
 ?
1.14.13.22 cyclohexanone + NADPH + O2
-
 Acinetobacter sp. 6-hexanolide + NADP+ + H2O
-
 ?
1.14.13.22 D-fenchone + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
1.14.13.22 syn-7-benzyloxymethyl-2-norbonen-5-one + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?

Cofactor

EC Number Cofactor Comment Organism Structure
1.14.13.22 FAD
-
 Acinetobacter sp.
1.14.13.22 NADPH electron donor Acinetobacter sp.