Literature summary extracted from

Wust, M.; Little, D.B.; Schalk, M.; Croteau, R.
Hydroxylation of limonene enantiomers and analogs by recombinant (-)-limonene 3- and 6-hydroxylases from Mint (Mentha) species: Evidence for catalysis within sterically constrained active sites (2001), Arch. Biochem. Biophys., 387, 125-136.

Organism

EC Number	Organism	UniProt	Comment	Textmining
1.14.14.51	Mentha spicata	-	spearmint	-
1.14.14.99	Mentha x piperita	-	-	-

Substrates and Products (Substrate)

EC Number	Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
1.14.14.51	(-)-(4S)-limonene + NADPH + O2	-	Mentha spicata	(-)-(4R,6S)-trans-carveol + NADP+ + H2O	-	?
1.14.14.51	additional information	(4R)-limonene leads to multiple products indicating allylic rearrangement	Mentha spicata	?	-	?
1.14.14.99	(+)-limonene + [reduced NADPH-hemoprotein reductase] + O2	-	Mentha x piperita	(+)-trans-isopiperitenol + [oxidized NADPH-hemoprotein reductase] + H2O	-	?
1.14.14.99	(-)-(4S)-limonene + [reduced NADPH-hemoprotein reductase] + O2	highly specific, regiospecific and stereospecific reaction	Mentha x piperita	(-)-trans-(3S,4R)-isopiperitenol + [oxidized NADPH-hemoprotein reductase] + H2O	-	?

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Release 2023.1 (January 2023)