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Literature summary extracted from

  • Croteau, R.B.; Shaskus, J.J.; Renstrom, B.; Felton, N.M.; Cane, D.E.; Saito, A.; Chang, C.
    Mechanism of the pyrophosphate migration in the enzymatic cyclization of geranyl and linalyl pyrophosphate to (+)- and (-)-bornyl pyrophosphate (1985), Biochemistry, 24, 7077-7085.
    View publication on PubMed

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
5.5.1.22 geranyl diphosphate Salvia officinalis
-
 (-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?
5.5.1.22 geranyl diphosphate Tanacetum vulgare
-
 (-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?

Organism

EC Number Organism UniProt Comment Textmining
5.5.1.8 Salvia officinalis
-
-
-
5.5.1.8 Tanacetum vulgare
-
-
-
5.5.1.22 Salvia officinalis
-
-
-
5.5.1.22 Tanacetum vulgare
-
-
-

Reaction

EC Number Reaction Comment Organism Reaction ID
5.5.1.8 geranyl diphosphate = (+)-bornyl diphosphate mechanism Salvia officinalis
a
5.5.1.8 geranyl diphosphate = (+)-bornyl diphosphate mechanism Tanacetum vulgare
a
5.5.1.8 geranyl diphosphate = (+)-bornyl diphosphate linalyl diphosphate is an intermediate Salvia officinalis
a
5.5.1.8 geranyl diphosphate = (+)-bornyl diphosphate linalyl diphosphate is an intermediate Tanacetum vulgare
a
5.5.1.8 geranyl diphosphate = (+)-bornyl diphosphate solely the diphosphate ester oxygen of geranyl diphosphate is involved in all the critical bonding processes in the coupled isomerization-cyclization Salvia officinalis
a
5.5.1.8 geranyl diphosphate = (+)-bornyl diphosphate solely the diphosphate ester oxygen of geranyl diphosphate is involved in all the critical bonding processes in the coupled isomerization-cyclization Tanacetum vulgare
a

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
5.5.1.8 Geranyl diphosphate
-
 Salvia officinalis (+)-Bornyl-diphosphate
-
 ?
5.5.1.8 Geranyl diphosphate
-
 Tanacetum vulgare (-)-Bornyl-diphosphate
-
 ?
5.5.1.22 (3S)-linalyl diphosphate
-
 Salvia officinalis (-)-bornyl diphosphate
-
 ?
5.5.1.22 (3S)-linalyl diphosphate
-
 Tanacetum vulgare (-)-bornyl diphosphate
-
 ?
5.5.1.22 geranyl diphosphate
-
 Salvia officinalis (-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?
5.5.1.22 geranyl diphosphate
-
 Tanacetum vulgare (-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?