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Literature summary extracted from

  • Croteau, R.; Satterwhite, D.M.; Cane, D.E.; Chang, C.C.
    Biosynthesis of monoterpenes: Enantioselectivity in the enzymatic cyclization of (+)- and (-)-linalyl pyrophospahte to (+)- and (-) pinene and (+)- and (-)-camphene (1988), J. Biol. Chem., 263, 10063-10071.
    View publication on PubMed

KM Value [mM]

EC Number KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
4.2.3.119 0.0023
-
 neryl diphosphate pH 7.2, 30°C Salvia officinalis
4.2.3.119 0.0031
-
 geranyl diphosphate pH 7.2, 30°C Salvia officinalis
4.2.3.119 0.0036
-
 (3S)-linalyl diphosphate pH 7.2, 30°C Salvia officinalis
4.2.3.119 0.0036
-
 (3R)-linalyl diphosphate pH 7.2, 30°C Salvia officinalis
4.2.3.120 0.0023
-
 neryl diphosphate pH 7.2, 30°C Salvia officinalis
4.2.3.120 0.0031
-
 geranyl diphosphate pH 7.2, 30°C Salvia officinalis
4.2.3.120 0.0036
-
 (3S)-linalyl diphosphate pH 7.2, 30°C Salvia officinalis
4.2.3.120 0.0036
-
 (3R)-linalyl diphosphate pH 7.2, 30°C Salvia officinalis

Organism

EC Number Organism UniProt Comment Textmining
4.2.3.116 Salvia officinalis
-
-
-
4.2.3.117 Salvia officinalis
-
-
-
4.2.3.119 Salvia officinalis
-
-
-
4.2.3.119 Salvia officinalis
-
 isoform cyclase II
-
4.2.3.120 Salvia officinalis
-
 isoform cyclase II
-
4.2.3.121 Salvia officinalis
-
-
-

Source Tissue

EC Number Source Tissue Comment Organism Textmining

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.2.3.116 (3R)-linalyl diphosphate (3R)-enantiomer is preferred over (3S)-enantiomer Salvia officinalis (+)-camphene + diphosphate products are (+)-camphene and (+)alpha-pinene ?
4.2.3.116 (3S)-linalyl diphosphate (3R)-enantiomer is preferred over (3S)-enantiomer Salvia officinalis (-)-camphene + diphosphate products are (-)-camphene and (-)alpha-pinene ?
4.2.3.116 geranyl diphosphate
-
 Salvia officinalis (+)-camphene + diphosphate products are (+)-camphene and (+)alpha-pinene ?
4.2.3.116 neryl diphosphate
-
 Salvia officinalis (+)-camphene + diphosphate products are (+)-camphene and (+)alpha-pinene ?
4.2.3.117 (3R)-linalyl diphosphate (3S)-enantiomer is preferred over (3R)-enantiomer Salvia officinalis (+)-camphene + diphosphate products are (-)-camphene and (-)alpha-pinene ?
4.2.3.117 (3S)-linalyl diphosphate (3S)-enantiomer is preferred over (3R)-enantiomer Salvia officinalis (+)-camphene + diphosphate products are (+)-camphene and (+)-alpha-pinene ?
4.2.3.117 geranyl diphosphate
-
 Salvia officinalis (-)-camphene + diphosphate products are (-)-camphene and (-)alpha-pinene ?
4.2.3.117 neryl diphosphate
-
 Salvia officinalis (-)-camphene + diphosphate products are (-)-camphene and (-)-alpha-pinene ?
4.2.3.119 (3R)-linalyl diphosphate (3S)-enantiomer is preferred over (3R)-enantiomer Salvia officinalis (+)-alpha-pinene + diphosphate products are (-)-camphene and (-)alpha-pinene ?
4.2.3.119 (3R)-linalyl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
4.2.3.119 (3S)-linalyl diphosphate (3S)-enantiomer is preferred over (3R)-enantiomer Salvia officinalis (+)-alpha-pinene + diphosphate products are (+)-camphene and (+)alpha-pinene ?
4.2.3.119 (3S)-linalyl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
4.2.3.119 geranyl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
4.2.3.119 geranyl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-camphene and (-)alpha-pinene ?
4.2.3.119 additional information substrates geranyl, neryl, and (3S)-linalyl diphosphate yield exclusively the (-)-isomer series, whereas (3R)-linalyl diphosphate affords the (+)-isomers at low rates Salvia officinalis ?
-
 ?
4.2.3.119 neryl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
4.2.3.119 neryl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-camphene and (-)alpha-pinene ?
4.2.3.120 (3R)-linalyl diphosphate
-
 Salvia officinalis (-)-beta-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
4.2.3.120 (3S)-linalyl diphosphate
-
 Salvia officinalis (-)-beta-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
4.2.3.120 geranyl diphosphate
-
 Salvia officinalis (-)-beta-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
4.2.3.120 additional information substrates geranyl, neryl, and (3S)-linalyl diphosphate yield exclusively the (-)-isomer series, whereas (3R)-linalyl diphosphate affords the (+)-isomers at low rates Salvia officinalis ?
-
 ?
4.2.3.120 neryl diphosphate
-
 Salvia officinalis (-)-beta-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
4.2.3.121 (3R)-linalyl diphosphate (3R)-enantiomer is preferred over (3S)-enantiomer Salvia officinalis (+)-alpha-pinene + diphosphate products are (+)-camphene and (+)alpha-pinene ?
4.2.3.121 (3S)-linalyl diphosphate (3R)-enantiomer is preferred over (3S)-enantiomer Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-camphene and (-)alpha-pinene ?
4.2.3.121 geranyl diphosphate
-
 Salvia officinalis (+)-alpha-pinene + diphosphate products are (+)-camphene and (+)alpha-pinene ?
4.2.3.121 neryl diphosphate
-
 Salvia officinalis (+)-alpha-pinene + diphosphate products are (+)-camphene and (+)alpha-pinene ?

Synonyms

EC Number Synonyms Comment Organism
4.2.3.116 cyclase I
-
 Salvia officinalis
4.2.3.117 cyclase II
-
 Salvia officinalis
4.2.3.119 cyclase II
-
 Salvia officinalis
4.2.3.121 cyclase I
-
 Salvia officinalis