Literature summary for 5.5.1.8 extracted from

Croteau, R.; Felton, N.M.; Wheeler, C.J.
Stereochemistry at C-1 of geranyl pyrophosphate and neryl pyrophosphate in the cyclization to (+)- and (-)-bornyl pyrophosphate (1985), J. Biol. Chem., 260, 5956-5962.

Search for more literature for 5.5.1.8

Organism

Organism	UniProt	Comment	Textmining
Salvia officinalis	-	-	-
Tanacetum vulgare	-	-	-

Reaction

Reaction	Comment	Organism	Reaction ID
geranyl diphosphate = (+)-bornyl diphosphate	mechanism	Salvia officinalis	a
geranyl diphosphate = (+)-bornyl diphosphate	mechanism	Tanacetum vulgare	a
geranyl diphosphate = (+)-bornyl diphosphate	geranyl diphosphate is first stereospecifically isomerized to linalyl diphosphate which, following rotation about C-2-B-3 to the cisoid conformer, cyclizes from the anti-endo configuration. Neryl diphosphate cyclizes either directly or via the linalyl intermediate without the attendant rotation	Salvia officinalis	a
geranyl diphosphate = (+)-bornyl diphosphate	geranyl diphosphate is first stereospecifically isomerized to linalyl diphosphate which, following rotation about C-2-B-3 to the cisoid conformer, cyclizes from the anti-endo configuration. Neryl diphosphate cyclizes either directly or via the linalyl intermediate without the attendant rotation	Tanacetum vulgare	a

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
Geranyl diphosphate	-	Salvia officinalis	(+)-Bornyl-diphosphate	-	?
Geranyl diphosphate	-	Tanacetum vulgare	(-)-Bornyl-diphosphate	-	?

Use of this online version of BRENDA is free under the CC BY 4.0 license. See terms of use for full details.

Release 2023.1 (January 2023)