Organism | UniProt | Comment | Textmining |
---|---|---|---|
Fischerella ambigua | A0A076N4W8 | - |
- |
Fischerella ambigua UTEX 19030 | A0A076N4W8 | - |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
3-geranyl-3-[(Z)-2-isocyanoethenyl]-1H-indole | - |
Fischerella ambigua | 12-epi-hapalindole U | - |
? | |
3-geranyl-3-[(Z)-2-isocyanoethenyl]-1H-indole | - |
Fischerella ambigua UTEX 19030 | 12-epi-hapalindole U | - |
? |
Synonyms | Comment | Organism |
---|---|---|
famC1 | - |
Fischerella ambigua |
General Information | Comment | Organism |
---|---|---|
physiological function | aromatic prenyltransferase FamD2 and FamC1 act in concert to form the tetracyclic core ring system of the hapalindoles from cis-indole isonitrile and geranyl diphosphate through a presumed biosynthetic Cope rearrangement and subsequent 6-exo-trig cyclization/electrophilic aromatic substitution reaction | Fischerella ambigua |