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Literature summary for 5.3.2.6 extracted from

  • Miao, Y.; Geertsema, E.M.; Tepper, P.G.; Zandvoort, E.; Poelarends, G.J.
    Promiscuous catalysis of asymmetric Michael-type additions of linear aldehydes to beta-nitrostyrene by the proline-based enzyme 4-oxalocrotonate tautomerase (2013), ChemBioChem, 14, 191-194.
    View publication on PubMed
Search for more literature for 5.3.2.6

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate Bacillus subtilis
-
 (3E)-2-oxohex-3-enedioate
-
 ?

Organism

Organism UniProt Comment Textmining
Bacillus subtilis
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate
-
 Bacillus subtilis (3E)-2-oxohex-3-enedioate
-
 ?
acetaldehyde + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (3S)-4-nitro-3-phenylbutanal
-
 ?
butanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R,3S)-2-ethyl-4-nitro-3-phenylbutanal
-
 ?
heptanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R)-2-[(1S)-2-nitro-1-phenylethyl]heptanal
-
 ?
hexanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R)-2-[(1S)-2-nitro-1-phenylethyl]hexanal
-
 ?
octanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R)-2-[(1S)-2-nitro-1-phenylethyl]octanal
-
 ?
pentanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R)-2-[(1S)-2-nitro-1-phenylethyl]pentanal
-
 ?
propanal + [(Z)-2-nitroethenyl]benzene
-
 Bacillus subtilis (2R,3S)-2-methyl-4-nitro-3-phenylbutanal
-
 ?

Synonyms

Synonyms Comment Organism
4-OT
-
 Bacillus subtilis
4-oxalocrotonate tautomerase
-
 Bacillus subtilis