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Literature summary for 4.99.1.2 extracted from

  • Walsh, C.; Begley, T.; Walts, A.
    Bacterial organomercurial lyase: Mechanistic studies on a protonolytic organomercurial cleaving enzyme in mercurial detoxification (1986), Stereochem. Org. Bioorg. Transform. (Proc. Workshop, Conf. Hoechst,17th Meeting, Bartmann, W. , Sharpless, K. , eds. ), 17, 73-83.
No PubMed abstract available
Search for more literature for 4.99.1.2

Metals/Ions

Metals/Ions Comment Organism Structure
additional information no associated metals Escherichia coli

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
organo-tin compounds Escherichia coli degradation of biocides, resistant organisms ?
-
 ?

Organism

Organism UniProt Comment Textmining
Escherichia coli
-
 overproducing strain
-
Escherichia coli overproducing
-
 overproducing strain
-

Reaction

Reaction Comment Organism Reaction ID
RHg+ + H+ = RH + Hg2+ mechanism Escherichia coli
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
alkyl mercuric halides + H+ primary, secondary, tertiary Escherichia coli ?
-
 ?
alkyl mercuric halides + H+ primary, secondary, tertiary Escherichia coli overproducing ?
-
 ?
cis-2-butenylmercuric chloride + H+
-
 Escherichia coli ?
-
 ?
crotonyl mercuric bromide + H+
-
 Escherichia coli crotonaldehyde + Hg2+ + Br-
-
 ?
crotonyl mercuric bromide + H+
-
 Escherichia coli overproducing crotonaldehyde + Hg2+ + Br-
-
 ?
methyl mercuric chloride + H+
-
 Escherichia coli CH4 + Hg2+ + Cl-
-
 ?
additional information not: dimethyl mercury Escherichia coli ?
-
 ?
additional information not: dimethyl mercury Escherichia coli overproducing ?
-
 ?
n-butyl mercurial + H+
-
 Escherichia coli ?
-
 ?
organo-tin compounds degradation of biocides, resistant organisms Escherichia coli ?
-
 ?
phenylmercuric chlorides + H+
-
 Escherichia coli ?
-
 ?
phenylmercuric chlorides + H+
-
 Escherichia coli overproducing ?
-
 ?
RHg+ + H+
-
 Escherichia coli RH + Hg2+
-
 ?
RHg+ + H+
-
 Escherichia coli overproducing RH + Hg2+
-
 ?
vinyl mercuric bromide + H+
-
 Escherichia coli ethene + Hg+ + Br-
-
 ?

Turnover Number [1/s]

Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
0.0167
-
 methyl mercuric chloride
-
 Escherichia coli
0.333
-
 n-butyl mercurial
-
 Escherichia coli
4
-
 cis-2-butenyl mercuric chloride
-
 Escherichia coli

Cofactor

Cofactor Comment Organism Structure
additional information no cofactors Escherichia coli