Literature summary for 4.5.1.B1 extracted from

Tang, X.; Zhang, R.; Zhang, Q.; Wang, W.
Dehydrochlorination mechanism of gamma-hexachlorocyclohexane degraded by dehydrochlorinase LinA from Sphingomonas paucimobilis UT26 (2016), RSC Adv., 6, 4183-4192 .

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Crystallization (Commentary)

Crystallization (Comment)	Organism
quantum mechanics/molecular mechanics study. In the degradation process, two discontinuous dehydrochlorination reactions with the Boltzmann-weighted average potential barriers of 16.2 and 17.3 kcal/mol are connected by a conformational transition with a barrier of 11.1 kcal /mol. Residue Phe68 facilitates the dehydrochlorination of gamma-hexachlorohexane, whereas Leu21 and Cys71 suppress it	Sphingobium indicum

Organism

Organism	UniProt	Comment	Textmining
Sphingobium indicum	P51697	-	-
Sphingobium indicum DSM 16413	P51697	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
gamma-hexachlorocyclohexane	-	Sphingobium indicum	1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl	-	?
gamma-hexachlorocyclohexane	-	Sphingobium indicum DSM 16413	1,3,4,6-tetrachloro-1,4-cyclohexadiene + 2 HCl	-	?

Synonyms

Synonyms	Comment	Organism
LinA	-	Sphingobium indicum

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Release 2023.1 (January 2023)