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Literature summary for 4.4.1.3 extracted from

  • Burkhardt, I.; Lauterbach, L.; Brock, N.; Dickschat, J.
    Chemical differentiation of three DMSP lyases from the marine Roseobacter group (2017), Org. Biomol. Chem., 15, 4432-4439 .
    View publication on PubMed

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
4.2
-
dimethylseleniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
5.7
-
3-(thiolan-1-ium-1-yl)propanoate 30°C, pH not specified in the publication Ruegeria pomeroyi
8
-
methylpropylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
8.2
-
diethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
10.7
-
ethylmethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
12.8
-
dimethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
16.4
-
diethylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
18.7
-
dimethylseleniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
21.4
-
dimethylseleniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
26.1
-
ethylmethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
27.8
-
methylpropylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
28.6
-
dimethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
31.4
-
diethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
31.4
-
3-(thiolan-1-ium-1-yl)propanoate 30°C, pH not specified in the publication Ruegeria pomeroyi
33.4
-
ethylmethylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
34.8
-
dimethylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
35.7
-
methylpropylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
102.6
-
3-(thiolan-1-ium-1-yl)propanoate 30°C, pH not specified in the publication Phaeobacter inhibens

Organism

Organism UniProt Comment Textmining
Phaeobacter inhibens
-
-
-
Phaeobacter inhibens DSM 17395
-
-
-
Ruegeria pomeroyi Q5LT18
-
-
Ruegeria pomeroyi Q5LW89
-
-
Ruegeria pomeroyi DSM 15171 Q5LT18
-
-
Ruegeria pomeroyi DSM 15171 Q5LW89
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
3-(thiolan-1-ium-1-yl)propanoate
-
Phaeobacter inhibens thiolane + acrylate
-
?
3-(thiolan-1-ium-1-yl)propanoate
-
Ruegeria pomeroyi thiolane + acrylate
-
?
3-(thiolan-1-ium-1-yl)propanoate
-
Ruegeria pomeroyi DSM 15171 thiolane + acrylate
-
?
3-(thiolan-1-ium-1-yl)propanoate
-
Phaeobacter inhibens DSM 17395 thiolane + acrylate
-
?
diethylsulfoniopropionate
-
Phaeobacter inhibens diethylsulfide + acrylate
-
?
diethylsulfoniopropionate
-
Ruegeria pomeroyi diethylsulfide + acrylate
-
?
diethylsulfoniopropionate
-
Ruegeria pomeroyi DSM 15171 diethylsulfide + acrylate
-
?
diethylsulfoniopropionate
-
Phaeobacter inhibens DSM 17395 diethylsulfide + acrylate
-
?
dimethylseleniopropionate
-
Phaeobacter inhibens dimethylselenide + acrylate
-
?
dimethylseleniopropionate
-
Ruegeria pomeroyi dimethylselenide + acrylate
-
?
dimethylseleniopropionate
-
Ruegeria pomeroyi DSM 15171 dimethylselenide + acrylate
-
?
dimethylseleniopropionate
-
Phaeobacter inhibens DSM 17395 dimethylselenide + acrylate
-
?
dimethylsulfoniopropionate
-
Phaeobacter inhibens dimethylsulfide + acrylate
-
?
dimethylsulfoniopropionate
-
Ruegeria pomeroyi dimethylsulfide + acrylate
-
?
dimethylsulfoniopropionate
-
Ruegeria pomeroyi DSM 15171 dimethylsulfide + acrylate
-
?
dimethylsulfoniopropionate
-
Phaeobacter inhibens DSM 17395 dimethylsulfide + acrylate
-
?
ethylmethylsulfoniopropionate
-
Phaeobacter inhibens ethylmethylsulfide + acrylate
-
?
ethylmethylsulfoniopropionate
-
Ruegeria pomeroyi ethylmethylsulfide + acrylate
-
?
ethylmethylsulfoniopropionate
-
Ruegeria pomeroyi DSM 15171 ethylmethylsulfide + acrylate
-
?
ethylmethylsulfoniopropionate
-
Phaeobacter inhibens DSM 17395 ethylmethylsulfide + acrylate
-
?
methylpropylsulfoniopropionate
-
Phaeobacter inhibens methylpropylsulfide + acrylate
-
?
methylpropylsulfoniopropionate
-
Ruegeria pomeroyi methylpropylsulfide + acrylate
-
?

Synonyms

Synonyms Comment Organism
dddP
-
Phaeobacter inhibens
DddQ
-
Ruegeria pomeroyi
DddW
-
Ruegeria pomeroyi

Turnover Number [1/s]

Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
0.93
-
dimethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
1.47
-
ethylmethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
1.58
-
3-(thiolan-1-ium-1-yl)propanoate 30°C, pH not specified in the publication Ruegeria pomeroyi
1.67
-
methylpropylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
1.71
-
diethylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
1.83
-
dimethylseleniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
2.04
-
3-(thiolan-1-ium-1-yl)propanoate 30°C, pH not specified in the publication Phaeobacter inhibens
2.07
-
ethylmethylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
2.22
-
diethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
3.73
-
methylpropylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
3.85
-
dimethylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
4.25
-
dimethylseleniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
10.9
-
methylpropylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
11.5
-
ethylmethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
11.9
-
diethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
16.8
-
dimethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
21.9
-
3-(thiolan-1-ium-1-yl)propanoate 30°C, pH not specified in the publication Ruegeria pomeroyi
31.2
-
dimethylseleniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi

kcat/KM [mM/s]

kcat/KM Value [1/mMs-1] kcat/KM Value Maximum [1/mMs-1] Substrate Comment Organism Structure
0.02
-
3-(thiolan-1-ium-1-yl)propanoate 30°C, pH not specified in the publication Phaeobacter inhibens
0.032
-
dimethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
0.05
-
3-(thiolan-1-ium-1-yl)propanoate 30°C, pH not specified in the publication Ruegeria pomeroyi
0.056
-
ethylmethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
0.06
-
methylpropylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
0.062
-
ethylmethylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
0.071
-
diethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
0.098
-
dimethylseleniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
0.104
-
diethylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
0.105
-
methylpropylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
0.111
-
dimethylsulfoniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
0.199
-
dimethylseleniopropionate 30°C, pH not specified in the publication Phaeobacter inhibens
1.08
-
ethylmethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
1.32
-
dimethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
1.35
-
methylpropylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
1.46
-
diethylsulfoniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi
3.82
-
3-(thiolan-1-ium-1-yl)propanoate 30°C, pH not specified in the publication Ruegeria pomeroyi
7.38
-
dimethylseleniopropionate 30°C, pH not specified in the publication Ruegeria pomeroyi