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Literature summary for 4.3.3.2 extracted from

  • Bernhardt, P.; OConnor, S.E.
    Synthesis and biochemical evaluation of des-vinyl secologanin aglycones with alternate stereochemistry (2009), Tetrahedron Lett., 50, 7118-7120.
    View publication on PubMedView publication on EuropePMC
Search for more literature for 4.3.3.2

Crystallization (Commentary)

Crystallization (Comment) Organism
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 Rauvolfia serpentina

Organism

Organism UniProt Comment Textmining
Rauvolfia serpentina P68175
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
methyl (2R,4S)-2-(2-methylpropoxy)-4-(2-oxoethyl)-3,4-dihydro-2H-pyran-5-carboxylate + tryptamine cis- and trans-isomers are equally well accepted as substrates Rauvolfia serpentina methyl (2R,4S)-2-(2-methylpropoxy)-4-[(1S)-2,3,4,9-tetrahydro-1H-beta-carbolin-1-ylmethyl]-3,4-dihydro-2H-pyran-5-carboxylate + H2O
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 ?
methyl (2R,4S)-2-(cyclohexyloxy)-4-(2-oxoethyl)-3,4-dihydro-2H-pyran-5-carboxylate + tryptamine significant preference for the trans-isomer Rauvolfia serpentina methyl (2R,4S)-2-(cyclohexyloxy)-4-[(1S)-2,3,4,9-tetrahydro-1H-beta-carbolin-1-ylmethyl]-3,4-dihydro-2H-pyran-5-carboxylate + H2O
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 ?
methyl (2R,4S)-2-ethoxy-4-(2-oxoethyl)-3,4-dihydro-2H-pyran-5-carboxylate + tryptamine cis- and trans-isomers are equally well accepted as substrates Rauvolfia serpentina methyl (2R,4S)-2-ethoxy-4-[(1S)-2,3,4,9-tetrahydro-1H-beta-carbolin-1-ylmethyl]-3,4-dihydro-2H-pyran-5-carboxylate + H2O
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 ?
methyl (2R,4S)-2-tert-butoxy-4-(2-oxoethyl)-3,4-dihydro-2H-pyran-5-carboxylate + tryptamine cis- and trans-isomers are equally well accepted as substrates Rauvolfia serpentina methyl (2R,4S)-2-tert-butoxy-4-[(1S)-2,3,4,9-tetrahydro-1H-beta-carbolin-1-ylmethyl]-3,4-dihydro-2H-pyran-5-carboxylate + H2O
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 ?
methyl (2S,4S)-2-(2-methylpropoxy)-4-(2-oxoethyl)-3,4-dihydro-2H-pyran-5-carboxylate + tryptamine cis- and trans-isomers are equally well accepted as substrates Rauvolfia serpentina methyl (2S,4S)-2-(2-methylpropoxy)-4-[(1S)-2,3,4,9-tetrahydro-1H-beta-carbolin-1-ylmethyl]-3,4-dihydro-2H-pyran-5-carboxylate + H2O
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 ?
methyl (2S,4S)-2-ethoxy-4-(2-oxoethyl)-3,4-dihydro-2H-pyran-5-carboxylate + tryptamine cis- and trans-isomers are equally well accepted as substrates Rauvolfia serpentina methyl (2S,4S)-2-ethoxy-4-[(1S)-2,3,4,9-tetrahydro-1H-beta-carbolin-1-ylmethyl]-3,4-dihydro-2H-pyran-5-carboxylate + H2O
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 ?
methyl (2S,4S)-2-tert-butoxy-4-(2-oxoethyl)-3,4-dihydro-2H-pyran-5-carboxylate + tryptamine cis- and trans-isomers are equally well accepted as substrates Rauvolfia serpentina methyl (2S,4S)-2-tert-butoxy-4-[(1S)-2,3,4,9-tetrahydro-1H-beta-carbolin-1-ylmethyl]-3,4-dihydro-2H-pyran-5-carboxylate + H2O
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 ?
secologanin + tryptamine
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 Rauvolfia serpentina 3-alpha(S)-strictosidine + H2O
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 ?

Synonyms

Synonyms Comment Organism
strictosidine synthase
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 Rauvolfia serpentina