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Literature summary for 4.3.1.2 extracted from

  • Akhtar, M.; Botting, N.P.; Cohen, M.A.; Gani, D.
    Enantiospecific synthesis of 3-substituted aspartic acids via enzymic amination of substituted fumaric acids (1987), Tetrahedron, 43, 5899-5908.
No PubMed abstract available
Search for more literature for 4.3.1.2

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
L-threo-3-methylaspartate Clostridium tetanomorphum
-
 ?
-
 ?

Organism

Organism UniProt Comment Textmining
Clostridium tetanomorphum
-
 ATCC 15920
-

Reaction

Reaction Comment Organism Reaction ID
L-threo-3-methylaspartate = mesaconate + NH3 stereochemical mechanism Clostridium tetanomorphum
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
3-fluoroaspartate
-
 Clostridium tetanomorphum fluorofumarate + NH3 not a good substrate ?
beta-ethylaspartate 3-ethylaspartate Clostridium tetanomorphum ?
-
 ?
ethylfumarate + NH3
-
 Clostridium tetanomorphum ?
-
 ?
iso-propylfumarate + NH3
-
 Clostridium tetanomorphum ?
-
 ?
L-threo-3-methylaspartate r Clostridium tetanomorphum mesaconate + NH3
-
 ?
L-threo-3-methylaspartate (2S,3S)-3-methylaspartic acid Clostridium tetanomorphum mesaconate + NH3
-
 ?
L-threo-3-methylaspartate
-
 Clostridium tetanomorphum ?
-
 ?
additional information catalytic rates for the enzymatic amination of fumarate and mesaconate are faster than the rates of the corresponding deamination reactions Clostridium tetanomorphum ?
-
 ?