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BRENDA support

Literature summary for 4.2.3.171 extracted from

  • Rinkel, J.; Rabe, P.; Garbeva, P.; Dickschat, J.S.
    Lessons from 1,3-hydride shifts in sesquiterpene cyclizations (2016), Angew. Chem. Int. Ed. Engl., 55, 13593-13596.
    View publication on PubMed

Organism

Organism UniProt Comment Textmining
Kitasatospora setae E4N7E5
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Kitasatospora setae DSM 43861 E4N7E5
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2E,6E)-farnesyl diphosphate + H2O (+)-corvol ether A i.e. (1R*,4S*,4aR*,7R*,8aR*)-4,7-dimethyl-1-(propan-2-yl)decahydro-1,7-epoxynaphthalene. The corvol ether is formed through reprotonation of the neutral intermediate Kitasatospora setae (+)-corvol ether A + diphosphate
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(2E,6E)-farnesyl diphosphate + H2O (+)-corvol ether A i.e. (1R*,4S*,4aR*,7R*,8aR*)-4,7-dimethyl-1-(propan-2-yl)decahydro-1,7-epoxynaphthalene. The corvol ether is formed through reprotonation of the neutral intermediate Kitasatospora setae DSM 43861 (+)-corvol ether A + diphosphate
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Synonyms

Synonyms Comment Organism
KSE_12950
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Kitasatospora setae