Literature summary for 4.2.3.162 extracted from

Rinkel, J.; Rabe, P.; Garbeva, P.; Dickschat, J.S.
Lessons from 1,3-hydride shifts in sesquiterpene cyclizations (2016), Angew. Chem. Int. Ed. Engl., 55, 13593-13596.

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Organism

Organism	UniProt	Comment	Textmining
Streptomyces viridochromogenes	-	UniParc: UPI0001B4D949	-
Streptomyces viridochromogenes DSM 40736	-	UniParc: UPI0001B4D949	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(2E,6E)-farnesyl diphosphate	(-)-alpha-amorphene i.e. (1S,4aR,8aS)-4,7-dimethyl-1-(propan-2-yl)-1,2,4a,5,6,8a-hexahydronaphthalene. Initial 1,6-cyclisation. Incubations with geranyl diphosphate and geranylgeranyl diphosphate gives no products	Streptomyces viridochromogenes	(-)-alpha-amorphene + diphosphate	-	?
(2E,6E)-farnesyl diphosphate	(-)-alpha-amorphene i.e. (1S,4aR,8aS)-4,7-dimethyl-1-(propan-2-yl)-1,2,4a,5,6,8a-hexahydronaphthalene. Initial 1,6-cyclisation. Incubations with geranyl diphosphate and geranylgeranyl diphosphate gives no products	Streptomyces viridochromogenes DSM 40736	(-)-alpha-amorphene + diphosphate	-	?

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Release 2023.1 (January 2023)