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Literature summary for 4.2.3.16 extracted from
- Mechanism of monoterpene cyclization: stereochemistry of the transformation of noncyclizable substrate analogs by recombinant (-)-limonene synthase, (+)-bornyl diphosphate synthase, and (-)-pinene synthase (2002), J. Mol. Catal. B, 19, 415-421.
No PubMed abstract available
Cloned(Commentary)
| Cloned (Comment) | Organism |
|---|---|
| expressed in Escherichia coli | Mentha spicata |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Mentha spicata | - |
spearmint | - |
Purification (Commentary)
| Purification (Comment) | Organism |
|---|---|
- |
Mentha spicata |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| 6,7-dihydrogeranyl diphosphate | - |
Mentha spicata | ? | - |
? |  |
| geranyl diphosphate | cyclization proceeds via preliminary isomerization to the bound tertiary intermediate 3S-linalyl diphosphate | Mentha spicata | (-)-(4S)-limonene + diphosphate | - |
? | |
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