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Literature summary for 4.2.3.157 extracted from

  • Riclea, R.; Citron, C.A.; Rinkel, J.; Dickschat, J.S.
    Identification of isoafricanol and its terpene cyclase in Streptomyces violaceusniger using CLSA-NMR (2014), Chem. Commun. (Camb.), 50, 4228-4230.
    View publication on PubMed

Organism

Organism UniProt Comment Textmining
Streptomyces violaceusniger G2P5T1
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Streptomyces violaceusniger Tü 4113 G2P5T1
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2E,6E)-farnesyl diphosphate + H2O (+)-isoafricanol i.e. (1aS,4aR,5R,7aS,7bR)-3,3,5,7b-tetramethyldecahydro-4aH-cyclopropa[e]azulen-4a-ol Streptomyces violaceusniger (+)-isoafricanol + diphosphate
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?
(2E,6E)-farnesyl diphosphate + H2O (+)-isoafricanol i.e. (1aS,4aR,5R,7aS,7bR)-3,3,5,7b-tetramethyldecahydro-4aH-cyclopropa[e]azulen-4a-ol Streptomyces violaceusniger Tü 4113 (+)-isoafricanol + diphosphate
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?