Literature summary for 4.2.3.13 extracted from

Agger, S.; Lopez-Gallego, F.; Schmidt-Dannert, C.
Diversity of sesquiterpene synthases in the basidiomycete Coprinus cinereus (2009), Mol. Microbiol., 72, 1181-1195.

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Cloned(Commentary)

Cloned (Comment)	Organism
expressed in Escherichia coli	Coprinopsis cinerea
expressed in Escherichia coli BL21(DE3) cells	Coprinopsis cinerea

Organism

Organism	UniProt	Comment	Textmining
Coprinopsis cinerea	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(2E,6E)-farnesyl diphosphate	-	Coprinopsis cinerea	delta-cadinene + diphosphate	major product	?
(2E,6E)-farnesyl diphosphate	-	Coprinopsis cinerea ATCC MYA-4618	delta-cadinene + diphosphate	major product	?
(2E,6E)-farnesyl diphosphate + H2O	Cop4 generates a tertiary cadinyl cation which upon deprotonation yields its major cyclization product delta-cadinene. The cadinyl cation reacts further to yield other cyclization products (beta-cubebene, cubebol , beta-copaene, sativene)	Coprinopsis cinerea	delta-cadinene + diphosphate	-	?
(2E,6E)-farnesyl diphosphate + H2O	Cop4 generates a tertiary cadinyl cation which upon deprotonation yields its major cyclization product delta-cadinene. The cadinyl cation reacts further to yield other cyclization products (beta-cubebene, cubebol , beta-copaene, sativene)	Coprinopsis cinerea ATCC MYA-4618	delta-cadinene + diphosphate	-	?

Synonyms

Synonyms	Comment	Organism
Cop4	-	Coprinopsis cinerea
delta-cadinene synthase	-	Coprinopsis cinerea

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Release 2023.1 (January 2023)