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Literature summary for 4.2.3.120 extracted from

  • Pyun, H.J.; Wagschal, K.C.; Jung, D.; Coates, R.M.; Croteau, R.
    Stereochemistry of the proton elimination in the formation of (+)- and (-)-alpha-pinene by monoterpene cyclases from sage (Salvia officinalis) (1994), Arch. Biochem. Biophys., 308, 488-496.
    View publication on PubMed

Organism

Organism UniProt Comment Textmining
Salvia officinalis
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-
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
geranyl diphosphate
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Salvia officinalis (-)-beta-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
additional information enzymes removes the C4-proS-hydrogen of the substrate, the C3 proton of the corresponding pinyl cation, with a stereoselectivity exceeding 78% in the formation of (-)-alpha-pinene Salvia officinalis ?
-
?

Synonyms

Synonyms Comment Organism
cyclase II
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Salvia officinalis