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Literature summary for 4.2.3.119 extracted from

  • Croteau, R.; Satterwhite, D.M.; Cane, D.E.; Chang, C.C.
    Biosynthesis of monoterpenes: Enantioselectivity in the enzymatic cyclization of (+)- and (-)-linalyl pyrophospahte to (+)- and (-) pinene and (+)- and (-)-camphene (1988), J. Biol. Chem., 263, 10063-10071.
    View publication on PubMed
Search for more literature for 4.2.3.119

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
0.0023
-
 neryl diphosphate pH 7.2, 30°C Salvia officinalis
0.0031
-
 geranyl diphosphate pH 7.2, 30°C Salvia officinalis
0.0036
-
 (3S)-linalyl diphosphate pH 7.2, 30°C Salvia officinalis
0.0036
-
 (3R)-linalyl diphosphate pH 7.2, 30°C Salvia officinalis

Organism

Organism UniProt Comment Textmining
Salvia officinalis
-
-
-
Salvia officinalis
-
 isoform cyclase II
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(3R)-linalyl diphosphate (3S)-enantiomer is preferred over (3R)-enantiomer Salvia officinalis (+)-alpha-pinene + diphosphate products are (-)-camphene and (-)alpha-pinene ?
(3R)-linalyl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
(3S)-linalyl diphosphate (3S)-enantiomer is preferred over (3R)-enantiomer Salvia officinalis (+)-alpha-pinene + diphosphate products are (+)-camphene and (+)alpha-pinene ?
(3S)-linalyl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
geranyl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
geranyl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-camphene and (-)alpha-pinene ?
additional information substrates geranyl, neryl, and (3S)-linalyl diphosphate yield exclusively the (-)-isomer series, whereas (3R)-linalyl diphosphate affords the (+)-isomers at low rates Salvia officinalis ?
-
 ?
neryl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-alpha-pinene, (-)-beta-pinene, and (-)-camphene ?
neryl diphosphate
-
 Salvia officinalis (-)-alpha-pinene + diphosphate products are (-)-camphene and (-)alpha-pinene ?

Synonyms

Synonyms Comment Organism
cyclase II
-
 Salvia officinalis