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BRENDA support

Literature summary for 4.2.1.B6 extracted from

  • Hamberg, M.
    Hidden stereospecificity in the biosynthesis of divinyl ether fatty acids (2005), FEBS J., 272, 736-743.
    View publication on PubMed

Organism

Organism UniProt Comment Textmining
Ranunculus lingua
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-
-

Source Tissue

Source Tissue Comment Organism Textmining
leaf
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Ranunculus lingua
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate an essentially complete loss of isotope is noted with the (14R)-deuterated precursor, whereas incubation of the 14(S)-deuterated precursor affords products that retained most of the deuterium label Ranunculus lingua (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. (11Z)-etheroleic acid, reaction with leaf homogenate ?