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Literature summary for 4.2.1.92 extracted from
- Mechanism of corn hydroperoxide isomerase: detection of 12,13(S)-oxido-9(Z),11-octadecanoic acid (1987), Biochim. Biophys. Acta, 920, 76-84.
No PubMed abstract available
Natural Substrates/ Products (Substrates)
| Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| (13S)-hydroperoxy-(9Z,11E)-octadecadienoic acid | Zea mays | - |
(12,13S)-oxido-(9Z,11)-octadecadienoic acid + H2O | - |
? |  |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Zea mays | - |
- |
- |
Source Tissue
| Source Tissue | Comment | Organism | Textmining |
|---|---|---|---|
| germ | - |
Zea mays | - |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| (13S)-hydroperoxy-(9Z,11E)-octadecadienoic acid | - |
Zea mays | (12S,13S)-oxido-(9Z,11)-octadecadienoic acid + H2O | spontaneous hydrolysis to 12-keto-13-hydroxy-(9Z)-octadecenoic acid (72% 13(R) and 28% 13(S)) | ? | |
| (13S)-hydroperoxy-(9Z,11E)-octadecadienoic acid | - |
Zea mays | (12,13S)-oxido-(9Z,11)-octadecadienoic acid + H2O | - |
? | |
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