Literature summary for 4.2.1.92 extracted from

Su, C.; Sahlin, M.; Oliw, E.H.
A protein radical and ferryl intermediates are generated by linoleate diol synthase, a ferric hemeprotein with dioxygenase and hydroperoxide isomerase activities (1998), J. Biol. Chem., 273, 20744-20751.

Search for more literature for 4.2.1.92

Organism

Organism	UniProt	Comment	Textmining
Gaeumannomyces graminis	-	enzyme additionally has dioxygenase activity	-

Reaction

Reaction	Comment	Organism	Reaction ID
(9Z,11E,15Z)-(13S)-hydroperoxyoctadeca-9,11,15-trienoate = (9Z,15Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate + H2O	mechanism	Gaeumannomyces graminis	a

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(8R)-hydroperoxy-(9Z,12Z)-octadecadienoic acid	-	Gaeumannomyces graminis	(7S,8S)-dihydroxy-(9Z,12Z)-octadecadienoic acid + H2O	-	?
(8R)-hydroperoxy-(9Z,12Z)-octadecadienoic acid	-	Gaeumannomyces graminis var. graminis	(7S,8S)-dihydroxy-(9Z,12Z)-octadecadienoic acid + H2O	-	?

Cofactor

Cofactor	Comment	Organism	Structure
heme	ferric heme iron	Gaeumannomyces graminis

Use of this online version of BRENDA is free under the CC BY 4.0 license. See terms of use for full details.

Release 2023.1 (January 2023)