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Literature summary for 4.2.1.121 extracted from

  • Crombie, L.; Morgan, D.O.; Smith, E.H.
    The enzymic formation of colneleic acid, a divinyl ether fatty acid: experiments with [(9S)-18O2]hydroperoxyoctadeca-(10E),(12Z)-dienoic acid (1987), J. Chem. Soc. Chem. Commun., 1987, 502-503.
No PubMed abstract available
Search for more literature for 4.2.1.121

Organism

Organism UniProt Comment Textmining
Solanum tuberosum
-
-
-

Reaction

Reaction Comment Organism Reaction ID
(9S,10E,12Z)-9-hydroperoxyoctadeca-10,12-dienoate = (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoate + H2O the oxygen inserted enzymically between carbons 9- and 10- of the C-18 chain in forming colneleic acid originates from 18O2 gas via the hydroperoxide group of linoleic acid. A mechanism is proposed Solanum tuberosum
a

Source Tissue

Source Tissue Comment Organism Textmining
tuber
-
 Solanum tuberosum
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate
-
 Solanum tuberosum (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoic acid + H2O i.e. colneleate ?