Organism | UniProt | Comment | Textmining |
---|---|---|---|
Streptomyces coelicolor | Q9X839 | C-terminal domain; germacradienol/germacrene D synthase | - |
Reaction | Comment | Organism | Reaction ID |
---|---|---|---|
(1E,4S,5E,7R)-germacra-1(10),5-dien-11-ol + H2O = (-)-geosmin + acetone | conversion of germacradienol to geosmin results in the release of the three-carbon side chain as acetone and involves a 1,2-hydride shift of the bridgehead hydrogen exclusively into ring B of geosmin | Streptomyces coelicolor |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(1E,4S,5E,7R)-germacra-1(10),5-dien-11-ol + H2O | catalysed by the C-terminal domain of the bifunctional enzyme | Streptomyces coelicolor | (-)-geosmin + acetone | - |
? | |
additional information | conversion of germacradienol to geosmin results in the release of the three-carbon side chain as acetone and involves a 1,2-hydride shift of the bridgehead hydrogen exclusively into ring B of geosmin | Streptomyces coelicolor | ? | - |
? |