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Literature summary for 4.1.2.38 extracted from

  • Dominguez de Maria, P.; Stillger, T.; Pohl, M.; Kiesel, M.; Liese, A.; Groeger, H.; Trauthwein, H.
    Enantioselective C-C bond ligation using recombinant Escherichia coli-whole-cell biocatalysts (2008), Adv. Synth. Catal., 350, 165-173.
No PubMed abstract available

Cloned(Commentary)

Cloned (Comment) Organism
-
Pseudomonas fluorescens

Metals/Ions

Metals/Ions Comment Organism Structure
Mg2+
-
Pseudomonas fluorescens

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
2-hydroxy-1,2-diphenylethanone Pseudomonas fluorescens
-
benzaldehyde
-
r

Organic Solvent Stability

Organic Solvent Comment Organism
1-octanol log P value 3.0, half life 60 h Pseudomonas fluorescens
cyclohexane log P value 2.7, half life 10 h Pseudomonas fluorescens
dibutyl ether log P value 1.4, half life 670 h Pseudomonas fluorescens
dichloromethane log P value 1.5, half life 3 h Pseudomonas fluorescens
diethyl ether log P value 0.8, half life 240 h Pseudomonas fluorescens
diisopropyl ether log P value 2.6, half life 50 h Pseudomonas fluorescens
Ethyl acetate log P value 0.7, half life 12 h Pseudomonas fluorescens
heptane log P value 3.3, half life 5 h Pseudomonas fluorescens
isohexane log P value 3.9, half life 15 h Pseudomonas fluorescens
tert-butyl methyl ether log P value 1.0, half life 750 h Pseudomonas fluorescens
tetrahydrofuran log P value 0.4, half life 0 h Pseudomonas fluorescens
toluene log P value 2.3, half life 1 h Pseudomonas fluorescens

Organism

Organism UniProt Comment Textmining
Pseudomonas fluorescens
-
-
-

Purification (Commentary)

Purification (Comment) Organism
-
Pseudomonas fluorescens

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2-hydroxy-1,2-diphenylethanone
-
Pseudomonas fluorescens benzaldehyde
-
r
benzaldehyde + 2,2-dimethoxyacetaldehyde
-
Pseudomonas fluorescens 3,3-dimethoxy-2-hydroxy-1-phenyl-propanone
-
?
benzaldehyde + acetaldehyde
-
Pseudomonas fluorescens 2-hydroxy-1-phenylpropanone
-
?
furan-2-aldehyde + 2,2-dimethoxyacetaldehyde
-
Pseudomonas fluorescens 3,3-dimethoxy-2-hydroxy-1-furan-2-yl-propanone
-
?

Synonyms

Synonyms Comment Organism
BAL
-
Pseudomonas fluorescens
benzaldehyde lyase
-
Pseudomonas fluorescens

Temperature Optimum [°C]

Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
20
-
activity assay Pseudomonas fluorescens

pH Optimum

pH Optimum Minimum pH Optimum Maximum Comment Organism
8
-
activity assay Pseudomonas fluorescens

Cofactor

Cofactor Comment Organism Structure
thiamine diphosphate
-
Pseudomonas fluorescens