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Literature summary for 4.1.2.10 extracted from
- Stereoselective biocatalytic synthesis of (S)-2-hydroxy-2-methylbutyric acid via substrate engineering by using "thio-disguised" precursors and oxynitrilase catalysis (2007), Chemistry, 13, 3369-3376.
Natural Substrates/ Products (Substrates)
| Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| cyanide + benzaldehyde | Prunus dulcis | - |
(R)-mandelonitrile | - |
? |  |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Prunus dulcis | - |
- |
- |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| cyanide + 3-tetrahydrothiophenone | the enzyme, that shows (R)-stereospecificity for its natural substrate shows S-stereselectivity with the heterocyclic ketone as substrate | Prunus dulcis | (S)-3-hydroxytetrahydrothiophene-3-carbonitrile | - |
? | |
| cyanide + benzaldehyde | - |
Prunus dulcis | (R)-mandelonitrile | - |
? | |
Synonyms
| Synonyms | Comment | Organism |
|---|---|---|
| (R)-selective HNL | - |
Prunus dulcis |
| PaHNL | - |
Prunus dulcis |
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